高品质间苯二甲酰氯合成及脱色研究  

Synthesis and Discoloration of High Quality Isophthaloyl Dichloride

作　　者：欧阳宇迪 刘国文 周锦萍 罗先福 王燕 李萍 周亮 臧阳陵 OU YANG Yu-di;LIU Guo-wen;ZHOU Jin-ping;LUO Xian-fu;WANG Yah;LI Ping;ZHOU Liang;ZANG Yang-ling(Hunan Haili Chemical Industry Co.,Ltd.,Changsha 410007,China;Hunan Research Institute of Chemical Industry Co.,Ltd.,Nation Engineering Research Center for Agrochemicals,Changsha 410014,China;Hunan Province Key Laboratory for Agrochemicals,Changsha 410014,China)

机构地区：[1]湖南海利化工股份有限公司,湖南长沙410007 [2]湖南化工研究院有限公司国家农药创制工程技术研究中心,湖南长沙410014 [3]农用化学品湖南省重点实验室,湖南长沙410014

出　　处：《精细化工中间体》2018年第3期40-43,共4页Fine Chemical Intermediates

基　　金：湖南省科技重大专项(2016GK1001)

摘　　要：研究了以光气和间苯二甲酸为原料,N,N-二甲基甲酰胺(DMF)为催化剂,合成间苯二甲酰氯及产品脱色工艺。探讨了石英砂、无水硫酸钠、活性炭、DMF盐酸盐等脱色剂对产品间苯二甲酰氯颜色的影响。确证了以DMF盐酸盐作为产品脱色剂时,可得无色稳定的产品,精馏后产品含量99%以上,该工艺具有"三废"少、可循环套用、处理成本低等优点,适合工业化生产。Isophthaloyl dichloride was obtained from the reaction of isophthalic acid with phosgene using dimethylformamide as catalyst. The discoloration of isophthaloyl dichloride was studied. Discoloration agents product including silica sand, sodium sulfate anhydrous, activated carbon, DMF hydrochloride were tested. A colorless and stable product was obtained using DMF hydrochloride as discoloration reagent. After distillation, the colour of product was stable and the purity of product was of more than 99%. This method was suitable for industrial production with advantages including less waste, easy recycling, and low cost.

关 键 词：间苯二甲酰氯 脱色 DMF盐酸盐 

分 类 号：TQ245.21[化学工程—有机化工]