亚磷酸酯阻燃剂的绿色合成  

Green Synthesis of Phosphite Flame Retardants

作　　者：王俊龙 徐洋[1] 黄小冬[1] 杨锦飞[1] 职慧珍[1] Wang Junlong;Xu Yang;Huang Xiaodong;Yang Jinfei;Zhi Huizhen(College of Chemistry Engineering,Nanjing University of Science and Technology,Nanjing 210094)

机构地区：[1]南京师范大学化学与材料科学学院,南京210023

出　　处：《塑料助剂》2018年第4期30-32,共3页Plastics Additives

摘　　要：以亚磷酸三甲酯和一缩二丙二醇为原料,采用有机胺为催化剂,制得三(一缩二丙二醇)亚磷酸酯。最佳的工艺条件为:三氯化磷和一缩二丙二醇的物料比为1:1,催化剂有机碱的用量为原料总质量的5%,反应温度为30～85℃,反应时间为5～8 h,产品收率达90.5%。Trimethyl （dipropylene glycol） phosphite was synthesized from trimethyl phosphite and dipropylene glycol using organic amine as a catalyst. The optimum process conditions are as follows： the ma- terial ratio between phosphorous trichloride and dipropylene glycol is 1：1, the catalyst of organic amine is 5% of the total mass of materials, the reaction temperature is 30-85℃, the reaction time is 5-8 hours, as a result, the obtained yield rate will be up to 90.5%.

关 键 词：阻燃剂 亚磷酸三甲酯 一缩二丙二醇 三(一缩二丙二醇)亚磷酸酯 

分 类 号：TQ314.248[化学工程—高聚物工业]