Immobilization of NZVI in polydopamine surface-modified biochar for adsorption and degradation of tetracycline in aqueous solution  

作　　者：XiangyuWang Weitao Lian Xin Sun Jun Ma Ping Ning 

机构地区：[1]Faculty of Environmental Science and Engineering, Kunming University of Science and Technology, Kunming 650500, China [2]School of Municipal and Environmental Engineering, State Key Laboratory of Urban Water Resources and Environment, Harbin Institute of Technology, Harbin 150090, China＊

出　　处：《Frontiers of Environmental Science & Engineering》2018年第4期87-97,共11页环境科学与工程前沿（英文）

基　　金：This research was supported by thc National Nature Science Foundation of China （Grant Nos. 51368025 and 51068011 ）.

摘　　要：Polydopamine/NZVl@biochar composite （PDA/NZVI@BC） with high removal efficiency of tetracycline （TC） in aqueous solutions was successfully synthesized, The resultant composite demonstrated high reactivity, excellent stability and reusability over the reaction course. Such excellent performance can be attributed to the presence of the huge surface area on biochar （BC）, which could enhance NZVI dispersion and prolong its longevity. The carbonyl group contained on the surface of bioehar could combine with the amino group on polydopamine（PDA）. The hydroxyl groups in PDA is able to enhance the dispersion and loading of NZVI on BC. Being modified by PDA, the hydrophilicity of biochar was improved. Among BC, pristine NZVI and PDA/NZVI（L-BC, PDA/ NZVI（a-,BC exhibited the highest activity for removal of TC. Compared with NZVI, the removal efficiency of TC could be increased by 55.9c- by using PDA/NZVI@BC under the same conditions. The optimal modification time of PDA was 813, and the ratio of NZVI to BC was 1：2. In addition, the possible degradation mechanism of TC was proposed, which was based on the analysis of degraded praducts by LC-MS. Difli,-rent importanl /actors impacling on TC removal （including mass ratio of NZVI to BC/PDA, initial concentration, pH value and the initial temperature of the solution） were investigated as well. Overall, this study provides a promising alternative material and environmental pollution management option for antibiotic wastewater treatment.Polydopamine/NZVl@biochar composite （PDA/NZVI@BC） with high removal efficiency of tetracycline （TC） in aqueous solutions was successfully synthesized, The resultant composite demonstrated high reactivity, excellent stability and reusability over the reaction course. Such excellent performance can be attributed to the presence of the huge surface area on biochar （BC）, which could enhance NZVI dispersion and prolong its longevity. The carbonyl group contained on the surface of bioehar could combine with the amino group on polydopamine（PDA）. The hydroxyl groups in PDA is able to enhance the dispersion and loading of NZVI on BC. Being modified by PDA, the hydrophilicity of biochar was improved. Among BC, pristine NZVI and PDA/NZVI（L-BC, PDA/ NZVI（a-,BC exhibited the highest activity for removal of TC. Compared with NZVI, the removal efficiency of TC could be increased by 55.9c- by using PDA/NZVI@BC under the same conditions. The optimal modification time of PDA was 813, and the ratio of NZVI to BC was 1：2. In addition, the possible degradation mechanism of TC was proposed, which was based on the analysis of degraded praducts by LC-MS. Difli,-rent importanl /actors impacling on TC removal （including mass ratio of NZVI to BC/PDA, initial concentration, pH value and the initial temperature of the solution） were investigated as well. Overall, this study provides a promising alternative material and environmental pollution management option for antibiotic wastewater treatment.

关 键 词：BIOCHAR POLYDOPAMINE NZVI Modification TETRACYCLINE 

分 类 号：TQ529[化学工程—煤化学工程] X703[环境科学与工程—环境工程]