离子液体共价键功能化氧化石墨烯负载催化材料催化反应研究进展  

Progress in Catalysis of Ionic Liquid Covalently Functionalized Graphene Oxide Supported Catalysts

作　　者：陈松丛[1] 韩峰 刘建华[3] 夏春谷[3] 马建霞[1] CHEN Song-cong;HAN Feng;LIU Jian-hua;XIA Chun-gu;MA Jian-xia(Lanzhou Library,Chinese Academy of Sciences,Lanzhou 730000,China;College of Chemistry and Material Science,Shandong Agricultural University,Taian 271018,China;Lanzhou Institute of Chemical Physics,Chinese Academy of Sciences,Lanzhou 730000,China)

机构地区：[1]中国科学院兰州文献情报中心,甘肃兰州730000 [2]山东农业大学化学与材料科学学院,山东泰安271018 [3]中国科学院兰州化学物理研究所羰基合成与选择氧化国家重点实验室,甘肃兰州730000

出　　处：《分子催化》2018年第4期382-396,共15页Journal of Molecular Catalysis(China)

基　　金：国家自然科学基金项目(No.21673260;21373248;71373260);甘肃省科技厅项目(17ZC1LA017)~~

摘　　要：氧化石墨烯由于其独特的结构和性能赋予了它作为催化剂的先天优势,功能化的氧化石墨烯为其应用领域的拓展和效果提升提供了更多的发展契机,成为目前的研究趋势,离子液体功能化的氧化石墨烯结合二者自身优势的基础上,并由于协同作用具有更加优异的催化性能,广泛应用于众多反应中.我们针对离子液体共价键功能化的氧化石墨烯负载催化剂常见的催化反应,包括环加成反应,氧化反应,偶联反应,酯交换反应,乌尔曼反应,重排反应,光催化和电催化在近年来的研究进展进行了相关综述.The unique structure and properties ofgraphene oxide give it inherent advantages as a catalyst. The func-tionalized graphene oxide provides more opportunities for development and improvement of its application fields. It has become the current research trend. The ionic liquids functionalized graphene oxide combines both its own ad-vantages with graphene oxide and ionic liquid and has more excellent catalytic performance due to synergistic effect. This review summarizes the common catalytic reactions of ionic liquid functionalized graphene oxide supported cata-lysts, including cycloaddition reaction, oxidation reaction, coupling reaction, transesterification reaction, Ullmann reaction, rearrangement reaction, photocatalysis and electrocatalysis reaction, etc.

关 键 词：氧化石墨烯 离子液体 催化 功能化 

分 类 号：O643.32[理学—物理化学]