邻苯二甲酸二环已酯分子印迹聚合物的合成及其吸附性能的研究  

Study On the Synthesis and Adsorption Properties of Dicyclohexyl Phthalate Molecular Imprinted Polymers

作　　者：陈惠芳 陈琳琳 吴丽荣 苏丽婷 谢志新 CHEN Hui-fang;CHEN Lin-lin;WU Li-rong;SU Li-ting;XlE Zhi-xin(Quanzhou Medical College,Quanzhou 362000,China)

机构地区：[1]泉州医学高等专科学校,泉州362000

出　　处：《海峡药学》2018年第9期79-81,共3页Strait Pharmaceutical Journal

基　　金：泉州医学高等专科学校校级科研项目(编号:XJ1312)

摘　　要：目的研究邻苯二甲酸二环已酯分子印迹聚合物的合成及其吸附性能。方法以邻苯二甲酸二环己酯(DCHP)为模板分子,功能单体为丙烯酰胺,交联剂和引发剂分别为乙二醇二甲基丙烯酸酯和偶氮二异丁腈,合成邻苯二甲酸二环己酯分子印迹聚合物(DCHP-MIPs),并对合成条件进行优化。结果当邻苯二甲酸二环己酯与丙烯酰胺、乙二醇二甲基丙烯酸酯比例为1∶8∶40,偶氮二异丁腈为25mg时,DCHP-MIPs对邻苯二甲酸二环己酯的特异性吸附效果最好。结论通过吸附动力学和选择性能吸附实验,考察了DCHP-MIPs对邻苯二甲酸二环己酯的结合性能和选择性能。OBJECTIVE To study the synthesis and Imprinted Polymers. METHDOS Dicyclohexyl Phthalate adsorption properties of Dicyclohexyl Phthalate Molecular （DCHP） was used as template molecule ,functional monomer was accylamide, crosslinking agent and initiator were ethylene glycol dimethaccylate and azodiisobutyronitrile, respectively,to synthesize dicyclohexyl phthalate molecular imprinted polymer （DCHP-MIPS） ,and the synthesis conditions were optimized. RESULTS The specific adsorption effect of DCHP-MIPS on dicyclohexyl phthalate was best when the ratio of dicyclohexyl phthalate to acrylamide and glycol dimethacreylate was 1 ： 8： 40, and azodiisobutyronitrile was 25mg. CONCLUSINON The binding and selection kinetics and selective adsorption experiments. properties of DCHP-MIPs were investigated by adsorption

关 键 词：邻苯二甲酸二环己酯 分子印迹聚合物 

分 类 号：R969.4[医药卫生—药理学]