A two-step approach to synthesis of Co（OH）2/γ-NiOOH/ reduced graphene oxide nanocomposite for high performance supercapacitors  

作　　者：Ke ZHAN Tong YIN Yuan XUE Yinwen TAN Yihao ZHOU Ya YAN Bin ZHAO 

机构地区：[1]School of Materials Science and Engineering, University of Shanghai for Science and Technology, 516 Jungong Road, Shanghai 200093, China [2]Shanghai Innovation Institute for Materials, Shanghai 200444, China

出　　处：《Frontiers of Materials Science》2018年第3期273-282,共10页材料学前沿（英文版）

基　　金：This work was financially supported by the National Natural Science Foundation of China （Grant Nos. 51605293 and 51702213） and the Natural Science Foundation of Shanghai （16ZR1423500）. The authors also acknowledge financial support from the Program for Associate Professor of Special Appointment （Young Eastern Scholar） at Shanghai Institutions of Higher Learning （QD2016013）.

摘　　要：A two-step approach was reported to fabricate cobaltous hydroxide/y- nickel oxide hydroxide/reduced graphene oxide （Co（OH）217-NiOOHIRGO） nanocompo- sites on nickel foam by combining the reduction of graphene oxide with the help of refux condensation and the subsequent hydrothermal of Co（OH）2 on RGO. The microstructural, surface morphology and electrochemical properties of the Co（OH）2/γ-NiOOH/RGO nanocomposite were investigated. The results showed that the surface of the first-step fabricated γ-NiOOH/RGO nanocomposites was uniformly coated by Co（OH）2 nanoflakes with lateral size of tens of nm and thickness of several nm. Co（OH）2/γ-NiOOHIRGO nanocomposite demonstrated a high specific capacitance （745 mF/cm= at 0.5 mAJcm2） and a cycling stability of 69.8% after 1000 cycles at 30 mV/cm2· γ-NiOOH/RGO//Co（OH）2/γ- NiOOH/RGO asymmetric supercapacitor was assembled, and maximum gravimetric energy density of 57.3 W.h/kg and power density of 66.1 kW/kg were achieved. The synergistic effect between the highly conductive graphene and the nanoflake Co（OH）2 structure was responsible for the high electrochemical performance of the hybrid electrode. It is expected that this research could offer a simple method to prepare graphene-based electrode materials.A two-step approach was reported to fabricate cobaltous hydroxide/y- nickel oxide hydroxide/reduced graphene oxide （Co（OH）217-NiOOHIRGO） nanocompo- sites on nickel foam by combining the reduction of graphene oxide with the help of refux condensation and the subsequent hydrothermal of Co（OH）2 on RGO. The microstructural, surface morphology and electrochemical properties of the Co（OH）2/γ-NiOOH/RGO nanocomposite were investigated. The results showed that the surface of the first-step fabricated γ-NiOOH/RGO nanocomposites was uniformly coated by Co（OH）2 nanoflakes with lateral size of tens of nm and thickness of several nm. Co（OH）2/γ-NiOOHIRGO nanocomposite demonstrated a high specific capacitance （745 mF/cm= at 0.5 mAJcm2） and a cycling stability of 69.8% after 1000 cycles at 30 mV/cm2· γ-NiOOH/RGO//Co（OH）2/γ- NiOOH/RGO asymmetric supercapacitor was assembled, and maximum gravimetric energy density of 57.3 W.h/kg and power density of 66.1 kW/kg were achieved. The synergistic effect between the highly conductive graphene and the nanoflake Co（OH）2 structure was responsible for the high electrochemical performance of the hybrid electrode. It is expected that this research could offer a simple method to prepare graphene-based electrode materials.

关 键 词：reflux condensation graphene cobaltous hydroxide SUPERCAPACITOR 

分 类 号：O611.64[理学—无机化学] TQ334.1[理学—化学]