高效率厚膜聚合物太阳电池的研究进展  

Research progress in high efficiency thick film polymer solar cells

作　　者：张通[1,2] 赵晓礼 杨小牛[1,2] Tong Zhang;Xiaoli Zhao;Xiaoniu Yang(State Key Laboratory on Polymer Physics and Chemistry,Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,Changchun 130022,China;Polymer Composite Engineering Laboratory,Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,Changchun 130022,China)

机构地区：[1]中国科学院长春应用化学研究所高分子物理与化学国家重点实验室,长春130022 [2]中国科学院长春应用化学研究所高分子复合材料工程实验室,长春130022

出　　处：《中国科学：化学》2018年第8期815-828,共14页SCIENTIA SINICA Chimica

基　　金：国家自然科学基金(编号:21574132;21504090)资助项目

摘　　要：聚合物太阳电池作为第三代光伏技术,具有轻、薄、柔的特点,在未来应用中极具潜力.目前聚合物太阳电池的最高能量转化效率已经超过13%,为未来的产业化发展奠定了基础.为了进一步实现聚合物太阳电池的规模化制备,发展适合于卷对卷印刷工艺的高效率厚膜聚合物太阳电池体系至关重要.本文结合现阶段富勒烯聚合物太阳电池体系、非富勒烯聚合物太阳电池体系和三元聚合物太阳电池体系的最新研究进展,从给受体材料分子设计、光敏层薄膜形貌、电池器件制备方法及工作机理等方面对高效率厚膜聚合物太阳电池的相关工作进行了系统介绍,并对未来高效率厚膜聚合物太阳电池的研究方向进行了展望.Polymer solar cells （PSCs） are considered as the most promising third-generation photovoltaic technology in the future due to their advantages such as light weight, thin film and flexibility. Nowadays, the power conversion efficiencies （PCE） of PSCs have pasted 13%, laying the foundation for their fab-scale production. To realize the scalable fabrication of PSCs, the key issue is developing high efficiency thick film PSCs compatibility to the roll-to-roll （R2R） printing process. In this article, different kinds of high efficiency thick film PSCs including fullerene PSCs, non- fullerene PSCs and ternary PSCs are reviewed according to the recent research progress. The relevant research works on the molecular design of donor and acceptor materials, morphology of photoactive layers, fabrication method and mechanism of solar cells devices are discussed. And the future prospect of the research on thick film PSCs is presented.

关 键 词：厚膜聚合物太阳电池 卷对卷印刷工艺 分子结构 光敏层形貌 器件性能 

分 类 号：TM914.4[电气工程—电力电子与电力传动]