含短碳链氟聚丙烯酸酯三防整理剂的合成及应用  

Synthesis and application of short-fluorinated polyacrylate water-and oil-repellent and soil release finishing agent

作　　者：何杰芳 赵修芳 陈焜 周向东[2] HE Jie-fang1, ZHAO Xiu-fang2, CHEN Kun3, ZHOU Xiang-dong2(1.School of Life Science, Guizhou Normal University, Guiyang 550001, China; 2.College of Textile and Clothing Engineering, Soochow University, Suzhou 215021, China; 3.Hangzhou Meigao Huayi Chemical Co., Ltd., Hangzhou 311231, China)

机构地区：[1]贵州师范大学生命科学学院,贵州贵阳550001 [2]苏州大学纺织与服装工程学院,江苏苏州215021 [3]杭州美高华颐化工有限公司,浙江杭州311231

出　　处：《印染》2018年第18期7-11,16,共6页China Dyeing and Finishing

摘　　要：以甲基丙烯酸六氟丁酯(TFBMA)、聚乙二醇丙烯酸酯(PEGA)、丙烯酸丁酯(BA)和甲基丙烯酸羟乙酯(HEMA)为原料,十六烷基三甲基氯化铵(CTAC)和AEO-9为乳化剂,过硫酸铵(APS)为引发剂,合成了拒水拒油易去污整理剂。通过单因素试验得到优化的合成工艺为:单体质量比m(TFBMA)∶m(PEGA)∶m(BA)∶m(HEMA)为60∶10∶25∶5,乳化剂CTAC与AEO-9以2∶3的质量比复配,质量为反应单体总质量的4%,引发剂APS质量为反应单体总质量的0.4%,反应温度为75℃,反应时间为4 h。经拒水拒油易去污整理剂整理后,涤纶织物的拒水性能为100分,拒油性能为5级,易去污性能为4级。The water- and oil-repellent and soil release finishing agent is synthesized by using hexafluoro- butyl methacrylate （TFBMA）, polyethylene glycol acrylate （PEGA）, butyl acrylate （BA） and hydroxyethyl methacrylate （HEMA） as raw materials, cetyltrimethyl ammonium chloride （CTAC） and AEO-9 as emulsifiers and ammonium persulfate （APS） as initiator. The optimum synthesis process is： rn（TFBMA） ：m（PEGA） ：m（BA） ：m（HEMA） of 60： 10： 25：5, emulsifier CTAC and AEO-9 are compounded in the mass ratio of 2：3, the mass ratio of CTAC and AEO-9 to the reaction monomers is 4%, the initiator APS is 0.4%, reaction at 75℃ for 4 h. After finishing with water- water repellent property of polyester fabric is 100 Grade 4. and oil-repellent and soil release finishing agent, the oil-repellency is Grade 5 and soil release property is

关 键 词：拒水整理 拒油整理 易去污整理 短碳链含氟化合物 整理剂 涤纶织物 

分 类 号：TS195.57[轻工技术与工程—纺织化学与染整工程]