Preparation of Sodium Cobalt Tetracarbonyl and Optimization of Process Conditions for Hydroesterification of Ethylene Oxide  

作　　者：Wen Liyuan Zhang Zhanjun Chen Xiaoping Wang Shiqin Yu Wenli 

机构地区：[1]Institute of Industrial Catalysis, Guangdong University of Petrochemical Technology, Maoming 525000 [2]National Quality Supervision and Inspection Center of Dangerous Chemicals (Guangdong), Maoming 525000

出　　处：《China Petroleum Processing & Petrochemical Technology》2018年第3期78-84,共7页中国炼油与石油化工（英文版）

基　　金：supported by the Guangdong Province Natural Science Foundation (No.10152500002000019);the Maoming City Science and Technology Planning Project(No.2014069)

摘　　要：In this paper, sodium cobalt tetracarbonyl （NaCo（CO）4） was synthesized by using sodium dithionite and zinc powder as the reduction system and cobalt hexahydrate acetate as the precursor in the presence of methanol solvent. Methyl 3-hydroxypropionate was synthesized via hydroesterification of ethylene oxide （EO） catalyzed by NaCo（CO）4. The influencing factors on the reaction results were discussed, including the different ligands, the molar ratio of solvent and ethylene oxide, the reaction temperature, the reaction time, and the reaction pressure. An optimal catalytic system was obtained by using 3-hydroxypyridine as the ligoad under reaction conditions covering a reaction temperature 65 ℃, a reaction time of 7 h, a reaction pressure of 6 MPa, and a methoaol/EO molar ratio of 3：2. Under the optimal conditions, the conversion of ethylene oxide was equal to 97.86%, while the selectivity and yield of methyl 3-hydroxypropionate reached 88.19% and 86.30%, respectively. Finally, the reaction mechanism of hydroesterification of ethylene oxide catalyzed by NaCo（CO）4 was proposed.In this paper, sodium cobalt tetracarbonyl(NaCo(CO)_4) was synthesized by using sodium dithionite and zinc powder as the reduction system and cobalt hexahydrate acetate as the precursor in the presence of methanol solvent. Methyl 3-hydroxypropionate was synthesized via hydroesterification of ethylene oxide(EO) catalyzed by NaCo(CO)_4. The influencing factors on the reaction results were discussed, including the different ligands, the molar ratio of solvent and ethylene oxide, the reaction temperature, the reaction time, and the reaction pressure. An optimal catalytic system was obtained by using 3-hydroxypyridine as the ligand under reaction conditions covering a reaction temperature 65 °C, a reaction time of 7 h, a reaction pressure of 6 MPa, and a methanol/EO molar ratio of 3:2. Under the optimal conditions, the conversion of ethylene oxide was equal to 97.86%, while the selectivity and yield of methyl 3-hydroxypropionate reached 88.19% and 86.30%, respectively. Finally, the reaction mechanism of hydroesterification of ethylene oxide catalyzed by NaCo(CO)_4 was proposed.

关 键 词：sodium cobalt tetracarbonyl optimization HYDROESTERIFICATION reaction mechanism 

分 类 号：TQ225.24[化学工程—有机化工]