铑催化的三元碳环的开环/羰基环化反应研究进展  

Progress in Ring-opening/Carbonyl Cyclization of Rh Catalyzed Ternary Carbon Ring

作　　者：陈莹莹 毛国梁 刘小兵 吴韦 CHEN Ying-ying;MAO Guo-liang;LIU Xiao-bing;WU Wei(Provincial Key Laboratory of Oil ＆ Gas Chemical Technology,College of Chemistry and Chemical Engineering,Northeast Petroleum University,Daqing 163318,China)

机构地区：[1]东北石油大学化学化工学院石油与天然气化工省重点实验室

出　　处：《化学试剂》2018年第10期913-920,984,共9页Chemical Reagents

基　　金：国家自然科学基金资助项目(U1362110)

摘　　要：由于较大的环张力,三元环表现出较高的反应活性,在铑等过渡金属的催化作用下可以发生开环反应,然后与一氧化碳作用可实现羰基化,为制备多种具有生物活性的化合物提供了简便方法。主要综述了近年来铑催化的三元碳环衍生物和一氧化碳进行羰基化环化反应的研究进展、机理及其在有机合成中的应用。Due to the larger ring tension,the three membered ring showed high reactive activity,and the ring opening reaction could occur under the catalysis of the transition metals such as rhodium.Carbonylation and other reactions can be realized with the role of carbon monoxide.It also provides a simple synthesis method for a variety of bioactive compounds.In this work,the research progress,mechanism and application in the organic synthesis of rhodium catalyzed carbonylation cyclization of three membered carbon ring derivatives and carbon monoxide are reviewed.

关 键 词：三元碳环化合物 铑催化剂 羰基化反应 环化反应 

分 类 号：O62[理学—有机化学]