用于烯烃环氧化反应的甲基三氧化铼催化体系的研究进展  

The research progress in catalytic system of methyltrioxorhenium for olefin epoxidation

作　　者：刘伟[1,2] 钱静怡[3] 曹新宇 郭云飞 赵国升 LIU Wei;QIAN Jing-yi;CAO Xin-yu;GUO Yun-fei;ZHAO Guo-sheng(Key Laboratory of Environmental Materials and Pollution Control,Jilin Normal University,Siping 136000,China;College of Environment Science and Engineering,Jilin Normal Lniversity,Siping 136000,China;College of Chemistry,Jilin Normal University,Siping 136000,China)

机构地区：[1]吉林师范大学环境材料与污染控制吉林省高校重点实验室,吉林四平136000 [2]吉林师范大学环境科学与工程学院,吉林四平136000 [3]吉林师范大学化学学院,吉林四平136000

出　　处：《吉林师范大学学报（自然科学版）》2018年第4期24-29,共6页Journal of Jilin Normal University:Natural Science Edition

基　　金：吉林省科技发展计划项目(20180520147JH);四平市科技发展计划项目(2017094);吉林师范大学科研计划项目(吉师博2017021号);吉林师范大学大学生创新创业训练计划项目(S2017-77)

摘　　要：综述了甲基三氧化铼(MTO)与电子给予体共催化体系、MTO配合物/复合物催化体系和负载型MTO催化体系在选择性环氧化烯烃反应中的应用.以环境友好试剂H2O2或者UHP为氧化剂时,不同MTO催化体系均表现出很好的催化性能,其中电子给予体对MTO催化性能有很大影响,并且可以通过改变电子给予体的碱性来调控催化体系的稳定性、催化活性和选择性,还可以通过引入手性电子给予体实现对烯烃的不对称环氧化,负载型MTO催化体系的催化性能也与载体上的活性配位点的碱性密切相关.This article reviewed the application methyltrioxorhenium （MTO） and electron donor catalytic system,the MTO complex/compound catalytic system and loaded MTO catalytic system in the reaction of epoxidize alkenes selectively. Adopting environmentally friendly reagent H2O2, UHP as oxidant, clifferent MTO catalytic system showed a good catalytic performance, electron donor has a great influence on the MTO catalyst performanee, and we can regulate the stability, catalytic activity and selectivity of the catalyst by changing the basic of the electron donor, and realize asymmetric epoxidation of alkenes by introducing ehiral electron donor. The catalytic performance of the loaded MTO catalytic system is closely related to the alkaline of the active coordination site of the carrier.

关 键 词：甲基三氧化铼 催化 烯烃 环氧化 

分 类 号：O621.3[理学—有机化学]