Palladium（o）-Catalyzed Si-Si Bond Insertion by the Terminal Nitrogen of Diazo Compoundst  

作　　者：Zhenxing Liu Tianren Fu Jingfeng Huo Sheng Feng Jianbo Wang 

机构地区：[1]Beijing National Laboratory of Molecular Sciences (BNLMS) and Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871,China

出　　处：《Chinese Journal of Chemistry》2018年第10期945-949,共5页中国化学（英文版）

基　　金：The project is supported by the National Basic Research Pro- gram of China （973 Program, No. 2015CB856600） and the Natio- anal Natural Science Foundation of China （Grant 21332002, 21472004）.

摘　　要：The palladium（o）-catalyzed nitrogen insertion into cyclic Si-Si bonds has been realized by using N-tosylhydrazones/diazo compounds as the nitrogen source. The palladium（Ⅱ） nitrene formation and subsequent migratory insertion process are proposed as the key steps for this reaction.The palladium（o）-catalyzed nitrogen insertion into cyclic Si-Si bonds has been realized by using N-tosylhydrazones/diazo compounds as the nitrogen source. The palladium（Ⅱ） nitrene formation and subsequent migratory insertion process are proposed as the key steps for this reaction.

关 键 词：INSERTION diazo compounds Si-Si bond palladium catalysts palladium（Ⅱ） nitrene CARBENES 

分 类 号：TS802.8[轻工技术与工程] O643.36[理学—物理化学]