Assembly of a Heteronuclear POM {[K_(5)Na_(6)Cu^(Ⅱ)_(5)(CH_(3)COO)_(20)(CH_(3)CN)]Cl}_(n) via Two Kinds of Clusters as the Basic Bridge Unit  

作　　者：DAI Yu-Mei XU Jie 

机构地区：[1]Minnan Science and Technology Institute,Fujian Normal University,Quanzhou 362332,China

出　　处：《Chinese Journal of Structural Chemistry》2018年第10期1612-1618,共7页结构化学(英文)

基　　金：financially supported by the Youth Teachers'Training Foundation of Minnan Science and Technology Institute;Young and Middle-age academic leader plan of Quanzhou university;the undergraduate education teaching reform in Fujian province(2017)

摘　　要：A novel 3D hetero-nuclear framework,namely{[K_(5)Na_(6)Cu^(Ⅱ)_(5)(CH_(3)COO)_(20)(CH_(3)CN)]Cl}_(n)(1),was obtained by hydrothermal reaction.Triple metal centers(including sodium/potassium or/and copper)were coordinated to acetate anions in such two heteronuclear clusters,respectively.Moreover,nine kinds of binding modes for acetate anions were illustrated in polymer 1,with the first reported pentadentate coordination mode for acetate ligand.

关 键 词：hydrothermal synthesis acetate Hgand heteronuclear clusters of sodium/potassium and copper 

分 类 号：O641.4[理学—物理化学]