Fine controllable blue emission and its mechanism in Ce^(3+)-doped orthosilicate solid solution phosphors for different plant growths  

作　　者：Yaru Yang Yiting Lin Yue Han Zhongxian Qiu Wenli Zhou Jilin Zhang Chengzhi Li Liping Yu Shixun Lian 

机构地区：[1]Key Laboratory of Chemical Biology & Traditional Chinese Medicine Research (Ministry of Education),Key Laboratory of Sustainable Resources Processing and Advanced Materials of Hunan Province,College of Chemistry and Chemical Engineering,Hunan Normal University

出　　处：《Journal of Rare Earths》2018年第11期1150-1156,共7页稀土学报（英文版）

基　　金：Project supported by National Key Research and Development Program(2016YFB0302403);the National Natural Science Foundation of China(21571059);Natural Science Foundation of Hunan Province(2015JJ2100);Hunan Provincial Innovation Foundation for Postgraduate(CX2017B180)

摘　　要：The designed Ce^3＋-doped alkaline-earth silicate phosphors CamSr2 m-nBanSiO4：Ce^3＋,Li^＋ （CSBS：Ce^3＋） were synthesized by a high temperature solid-state reaction. The crystal field splitting and the centroid shift from the flee ion energy of 5d configuration were approximated from the spectrum for Ca2SiO4, Sr2SiO4 and Ba2SiO4 phosphors. The single-phase purity was checked by means of X-ray diffraction. Here, when the doped concentration of Ca2. is less than 80% （m 〈 1.6）, we report the structural phase transformation from monoclinic system [3-Ca2Si04 to orthorhombic system α′-Ca2SiO4. The phosphors excited by near-ultraviolet （NUV） light at wavelengths ranging from 200 to 400 nm demonstrate a broad asymmetric blue emission band. The emission peak wavelength redshifts firstly from 417 nm of Ca2SiO4 to 438 nm of Sro.3Cal.6SiO4, and then blueshifts to 411 nm of Sr2SiO4, and the end of 401 nm of Ba2SiOa. These results indicate that the tunable blue-emission of the phosphors can he realized through changing the solid solution components, which has a potential use as a blue component for fabricated precision modulation LEDs light sources and auxiliaries of SSC plastics films for different plant growths. We discuss in detail the possible mechanism and energy diagram of the tunable blue luminescence in CamSr2-M-nBaNSiO4：Ce^3＋.Li^＋ phosphors.The designed Ce^3＋-doped alkaline-earth silicate phosphors CamSr2 m-nBanSiO4：Ce^3＋,Li^＋ （CSBS：Ce^3＋） were synthesized by a high temperature solid-state reaction. The crystal field splitting and the centroid shift from the flee ion energy of 5d configuration were approximated from the spectrum for Ca2SiO4, Sr2SiO4 and Ba2SiO4 phosphors. The single-phase purity was checked by means of X-ray diffraction. Here, when the doped concentration of Ca2. is less than 80% （m 〈 1.6）, we report the structural phase transformation from monoclinic system [3-Ca2Si04 to orthorhombic system α′-Ca2SiO4. The phosphors excited by near-ultraviolet （NUV） light at wavelengths ranging from 200 to 400 nm demonstrate a broad asymmetric blue emission band. The emission peak wavelength redshifts firstly from 417 nm of Ca2SiO4 to 438 nm of Sro.3Cal.6SiO4, and then blueshifts to 411 nm of Sr2SiO4, and the end of 401 nm of Ba2SiOa. These results indicate that the tunable blue-emission of the phosphors can he realized through changing the solid solution components, which has a potential use as a blue component for fabricated precision modulation LEDs light sources and auxiliaries of SSC plastics films for different plant growths. We discuss in detail the possible mechanism and energy diagram of the tunable blue luminescence in CamSr2-M-nBaNSiO4：Ce^3＋.Li^＋ phosphors.

关 键 词：Ce^3＋ Controllable blue emission Alkaline-earth silicate Solid solution Plant growth Rare earths 

分 类 号：Q945[生物学—植物学] TQ422[化学工程]