Development of a microfluidic-chip system based on parallel flow for intensified Gd(Ⅲ)extraction from nitrate media using cationic extractant  

作　　者：All Abbasi Ahmad Rahbar-Kelishami Mohammad Javad Ghaserni 

机构地区：[1]Research lab for Advanced Separation Processes,Department of Chemical,Petroleum and Gas Engineering,Iron University of Science&Technology(IUST),Narmak 16846-13114,Tehran,Iran

出　　处：《Journal of Rare Earths》2018年第11期1198-1204,共7页稀土学报（英文版）

基　　金：Project supported by Department of Chemical,Petroleum and Gas Engineering,Iran University of Science&Technology(IUST)

摘　　要：Microfluidic solvent extraction （micro SX） of gadolinium was conducted using a mono- and diester mixture （MDEHPA） as the cationic extractant. A microfluidic Y-Y channel was fabricated using CO2- laser technique in a glass microchip used as the extraction system. Compared with batch extraction, extraction kinetic is found fast, and extraction equilibrium is attained within 15 s. Stoichiometry of the extracted complex is found to be Gd（NOs）3-3MDEHPA using log-log plot method. Additionally, the operating parameters and overall volumetric mass transfer coefficient （kLα） were investigated to determine the mass transfer performance. Optimal condition of microextraction for gadolinium using response surface methodology was determined （feed solutions 31 mg/L adjusted to pH value 2.5, extractant concentration 2.9 vol% and extraction time 13.5 s）. In optimal condition, gadolinium extraction yield is obtained 95.5%. Findings of this study approve simplicity, portability, effectiveness, swiftness, and environmental friendliness microfluidic solvent extraction process and reveal that micro SX is useful in the field of extraction strategic metals present at low concentrations, which are otherwise not technically amenable or economically feasible to extract using current traditional methods.Microfluidic solvent extraction （micro SX） of gadolinium was conducted using a mono- and diester mixture （MDEHPA） as the cationic extractant. A microfluidic Y-Y channel was fabricated using CO2- laser technique in a glass microchip used as the extraction system. Compared with batch extraction, extraction kinetic is found fast, and extraction equilibrium is attained within 15 s. Stoichiometry of the extracted complex is found to be Gd（NOs）3-3MDEHPA using log-log plot method. Additionally, the operating parameters and overall volumetric mass transfer coefficient （kLα） were investigated to determine the mass transfer performance. Optimal condition of microextraction for gadolinium using response surface methodology was determined （feed solutions 31 mg/L adjusted to pH value 2.5, extractant concentration 2.9 vol% and extraction time 13.5 s）. In optimal condition, gadolinium extraction yield is obtained 95.5%. Findings of this study approve simplicity, portability, effectiveness, swiftness, and environmental friendliness microfluidic solvent extraction process and reveal that micro SX is useful in the field of extraction strategic metals present at low concentrations, which are otherwise not technically amenable or economically feasible to extract using current traditional methods.

关 键 词：GADOLINIUM Solvent extraction Microfluidics Rare earth element （REE） Liquid phase microextraction CO2 engraving 

分 类 号：TS225.19[轻工技术与工程—粮食、油脂及植物蛋白工程] X523.02[轻工技术与工程—食品科学与工程]