二氧化双环戊二烯合成工艺与开发前景分析  

Analysis of Dicyclopentadienedoxide Synthesis Process and Its Developing Prospect

作　　者：瞿卫国[1] Qu Weiguo(SINOPEC Shanghai Petroleum Chemical Share Co.,Ltd,Shanghai 20054)

机构地区：[1]中国石化上海石油化工股份有限公司,上海200540

出　　处：《化工与医药工程》2018年第5期61-64,共4页Chemical and Pharmaceutical Engineering

摘　　要：简要介绍了二氧化双环戊二烯的用途与国内外生产现状,对以双环戊二烯为原料,通过氧化制备二氧化双环戊二烯的合成方法进行了概述,重点分析了H_2O_2/杂多酸类化合物法和钛硅分子筛催化氧化法的发展前景,最后就二氧化双环戊二烯的绿色生产工艺和开发方向提出适宜的建议。In this paper the use of dicyclopentadiene dioxide and its production status at home and abroad is briefly introduced. The synthesis method of dicyclopentadiene dioxide prepared by oxidation with dicyclopentadiene as raw material was described. The prospects of the method using H2O2/H2O and the method of using polyacid compounds and catalytic oxidation of titanium-silicon molecular sieves were emphatically analyzed. Finally, recommendations and proposals were presented for green production process and the developing direction of dicyclopentadiene dioxide.

关 键 词：双环戊二烯 二氧化双环戊二烯 氧化 发展前景 

分 类 号：O623.122[理学—有机化学]