CdSe量子点掺杂硼硅酸盐玻璃的光学性能  

Optical Properties of CdSe Quantum Dot-Doped Borosilicate Glass

作　　者：许周速[1] 程成[1] XU Zhousu, CHENG Cheng(Institute o f Intelligent Optoelectronic Technology, Zhejiang University o f Technology, Hangzhou 310014, China)

机构地区：[1]浙江工业大学光电子智能化技术研究所

出　　处：《硅酸盐学报》2018年第11期1529-1534,共6页Journal of The Chinese Ceramic Society

基　　金：浙江省自然科学基金项目(LY16F040005);国家自然科学基金项目(61474100);区域光纤通信网与新型光通信系统国家重点实验室开放研究课题;浙江工业大学校级教学改革项目(JG201729);浙江工业大学2016年度创新性实验项目

摘　　要：将CdO和ZnSe作为量子点引入前驱体,采用高温熔融冷却–热处理法,制备了CdSe量子点掺杂硼硅酸盐玻璃。透射电子显微镜测试表明,CdSe量子点呈六方晶结构。荧光光谱测试表明,CdSe量子点在可见波段存在本征发光和缺陷发光。随热处理温度增高,可以降低缺陷发光,提高量子点本征发光。研究了玻璃网络结构对CdSe量子点析晶影响。结果表明,随着B2O3含量增大,玻璃中二维（2D）网络结构增多,Cd^2＋和Se^2–移动能力增强,有利于量子点析出和表面缺陷钝化。CdSe量子点波长可调谐发光的特性,使得其有望作为在可见光波段的光增益介质。Borosilicate glasses doped with CdSe quantum dots （QDs） were prepared by a conventional melt-quenching process and subsequent heat treatment, using CdO and ZnSe as precursors of CdSe QDs. Based on the result by transmission electron microscopy （TEM）, CdSe QDs are hexagonal crystals. The result of photoluminescence （PL） spectra shows that CdSe QDs exhibit intrinsic luminescence and defect related luminescence in a visible band. The intensity of defect related to luminescence decreases, while the intensity of intrinsic luminescence of quantum dots increases with increasing heat-treatment temperature. The effect of glass network structure on the crystallization of CdSe QDs was investigated. The result shows that the two-dimensional （2D） network structure and the mobility of Cd^2＋ and Se〉 increase with increasing B203 concentration, which is conducive to the crystallization of QDs and the passivation of surface defect. The tunable PL emission of CdSe QDs-doped borosilicate glass could have a potential application as an optical gain material in the visible band.

关 键 词：硒化镉量子点 硼硅酸盐玻璃 玻璃网络结构 荧光寿命 析晶 

分 类 号：TN304.2[电子电信—物理电子学]