叠氮二异丁基铝及其配合物的制备与表征
Synthesis and Characterization of DiisobutylAluminum Azide and its Complex</em>
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<p class='author'><strong>作 者：</strong><a href='/writer/article.aspx?id=100000000828881' target='_blank' ><b class='type_ico_id'></b></a><a href='/zk/search.aspx?key=A%3d%5b%e9%ab%98%e5%8d%a0%e5%85%88%5d' title='高占先[1]'>高占先[1]</a> <a href='/writer/article.aspx?id=100000007194232' target='_blank' ><b class='type_ico_id'></b></a><a href='/zk/search.aspx?key=A%3d%5b%e5%86%af%e7%ab%8b%e6%98%a5%5d' title='冯立春[1]'>冯立春[1]</a> <a href='/writer/article.aspx?id=100000011855706' target='_blank' ><b class='type_ico_id'></b></a><a href='/zk/search.aspx?key=A%3d%5b%e5%bc%a0%e5%b0%8f%e8%88%aa%5d' title='张小航[1]'>张小航[1]</a> <em> </em></p><p class='organ'><strong>机构地区：</strong><a href='/organ/article.aspx?id=5973&subid=&showname=&searchtype=' target='_blank'><b class='type_ico_id'></b></a><a href='/zk/search.aspx?key=S%3d%e5%a4%a7%e8%bf%9e%e7%90%86%e5%b7%a5%e5%a4%a7%e5%ad%a6%e5%8c%96%e5%b7%a5%e5%ad%a6%e9%99%a2' title='[1]大连理工大学化工学院,辽宁大连116012'>[1]大连理工大学化工学院,辽宁大连116012</a> <em> </em></p><p class='from'><strong>出 处：</strong><a href='/journal/summary.aspx?gch=90247X' target='_blank'><b class='type_ico_id'></b></a><a href='/zk/search.aspx?key=J%3d%5b%e5%90%ab%e8%83%bd%e6%9d%90%e6%96%99%5d' title='含能材料'>《含能材料》</a>2002年第3期108-111,共4页<em>Chinese Journal of Energetic Materials</em></p><p class='fund'><strong>基 金：</strong>.NULL.</p><p class='abstrack'><strong>摘 要：</strong>通过三异丁基铝和四氯化碳反应制得氯化二异丁基铝。在芳烃溶液中,氯化二异丁基铝进一步和叠氮化钠反应合成了新化合物叠氮二异丁基铝(DBAA);以四氢呋喃为溶剂,合成DBAA时则得到了新化合物叠氮二异丁基铝和四氢呋喃的配合物(DBAA·THF)。用红外光谱、核磁共振谱等技术对这两个化合物的结构进行了表征;研究讨论了这些化合物的性质。<em><Abstrcat> Diisobutyl aluminum chloride is synthesized by the reaction of triisobutyl aluminum and carbon tetrachloride. Diisobutyl aluminum azide (DBAA) is synthesized by the reaction of the sodium azide and diisobutyl aluminum chloride in arenes, and its complex(DBAA·THF) is also synthesized through the reaction of the sodium azide and diisobutyl aluminum chloride in tetrahydrofuran. DBAA and DBAA·THF are characterized by IR and HNMR spectrum. The properties of DBAA and DBAA·THF are also studied. </em></p><p class='subject'><strong>关 键 词：</strong><a href='/zk/search.aspx?key=K%3d%5b%e5%8f%a0%e6%b0%ae%e4%ba%8c%e5%bc%82%e4%b8%81%e5%9f%ba%e9%93%9d%5d' title='叠氮二异丁基铝'>叠氮二异丁基铝</a> <a href='/subject/article.aspx?id=2882457' target='_blank'><b class='type_ico_id'></b></a><a href='/zk/search.aspx?key=K%3d%5b%e9%85%8d%e5%90%88%e7%89%a9%5d' title='配合物'>配合物</a> <a href='/zk/search.aspx?key=K%3d%5b%e9%ab%98%e5%90%ab%e8%83%bd%e6%9d%90%e6%96%99%5d' title='高含能材料'>高含能材料</a> <a href='/zk/search.aspx?key=K%3d%5bDBAA%5d' title='DBAA'>DBAA</a> <a href='/zk/search.aspx?key=K%3d%5b%e7%bb%93%e6%9e%84%e9%89%b4%e5%ae%9a%5d' title='结构鉴定'>结构鉴定</a> <a href='/subject/article.aspx?id=8585133' target='_blank'><b class='type_ico_id'></b></a><a href='/zk/search.aspx?key=K%3d%5bIR%e8%b0%b1%5d' title='IR谱'>IR谱</a> <a href='/zk/search.aspx?key=K%3d%5bHNMR%e8%b0%b1%5d' title='HNMR谱'>HNMR谱</a> </p><p class='class'><strong>分 类 号：</strong><a href='/zk/search.aspx?key=C%3dTB34' title='TB34'>TB34</a>[<a href = '/domain/article.aspx?id=563' >一般工业技术—材料科学与工程</a>] </p>
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