Synthesis and Crystal Structure of N-(5-Phenylseleno)pentyl Succinimide  

作　　者：张万轩 于海涛 等 

机构地区：[1]DepartmentofChemistry,NankaiUniversity,Tianjin300071,China

出　　处：《Chinese Journal of Structural Chemistry》2002年第5期517-519,共3页结构化学（英文）

基　　金：This work was supported by the NNSFC (No. 29832030)

摘　　要：N-(5-phenylseleno)pentyl succinimide 1, C15H19NO2Se (Mr = 324.27), was prepared by treating Br(CH2)5SePh with potassium succinimide. Its crystal structure has been determined by X-ray single-crystal diffraction. The crystal of 1 belongs to monoclinic system, space group P21/c with the crystal cell parameters: a = 18.018(6), b = 5.980(2), c = 14.682(5) ? = 109.977(6)? V = 1486.7(9) 3, Z = 4, Dc = 1.449 g/cm3, (MoK? = 2.523 mm-1, F(000) = 664,the final R = 0.0302 and wR = 0.0666 for 2623 independent observed reflections with I > 2(I). Structure analyses revealed that there exist strong nonclassical hydrogen bonds (CH…O).

关 键 词：N-(5-phenylseleno)pentyl succinimide PREPARATION crystal structure 

分 类 号：O626[理学—有机化学]