TMEDA存在下的异戊二烯阴离子均聚合动力学研究  

STUDY ON KINETIC OF ANIONIC POLYMERIZATION OF ISOPRENE IN PRESENCE OF TMEDA

作　　者：田福学[1] 张春庆[1] 曹民[1] 王润[1] 杨海涛[1] 方永刚[1] 

机构地区：[1]大连理工大学化工学院高分子材料系,辽宁大连116012

出　　处：《高分子材料科学与工程》2002年第5期80-83,共4页Polymer Materials Science & Engineering

摘　　要：研究了以 TMEDA(四甲基乙二胺 )为调节剂体系的异戊二烯阴离子均聚合动力学。获得了不同TMEDA/ Li及聚合温度对动力学的影响情况。从理论上对聚合机理进行了推导和验证 。The N,N,N′,N′ tetramethylethylenediamine(TMEDA) as polar additive of the anionic polymerization of isoprene initiated with n BuLi in cyclohexane was reported. The effects of TMEDA/Li (mole ratio) and reaction temperature on the polymerization rate were obtained. The polymerization mechanism was investigated in theory and confirmed by experiments. The polymerization active energies in different condition were obtained by Arrhenius equation.

关 键 词：TMEDA 异戊二烯 阴离子均聚合 动力学 研究 N N N' N’-四甲基乙二胺 

分 类 号：O631.5[理学—高分子化学] O632.14[理学—化学]