关于惰性电子对效应产生的原因探讨  

Discussion on the Reason for Indifferent Electronic Doublet Effect

作　　者：胥江河[1] 

机构地区：[1]重庆工商大学教务处,重庆400033

出　　处：《渝州大学学报（自然科学版）》2002年第3期32-37,共6页Journal of Yuzhou University(Natural Sciences Edition)

摘　　要：关于惰性电子对效应的产生原因目前有各种不同的解释 ,但通常都是采用单一的因素来分析 ,虽然也能说明部分事实 ,但认识比较片面。事实上随着这些元素形成化合物的类型不同 ,影响其氧化态变化的因素也是不同的 ,从热力学能量角度具体考虑不同情况下影响惰性电子对效应的主要因素 。There are various explanations for indifferent electroni c doublet effect, which can give the reasons partially for indifferent electroni c doublet effect on single factor and are somewhat one_sided. In fact, the influ ence factors of the oxidation state changes of these elements are different with the different types of the compounds from these elements. The relatively desira ble result has been obtained by taking the main factors, affecting the indiffere nt electronic doublet eeffect, into account under the different conditions from the angle of thermodynamics energy.

关 键 词：惰性电子对效应 电离能 氧化态 产生原因 热力学能量 离子化合物 共价化合物 

分 类 号：O611.3[理学—无机化学]