在含水介质中双核磺化酞菁铜(Ⅱ)催化氧化α-萘酚的研究  

Studies on Oxidation of α-Naphthol Catalyzed by Binnucleus Copper(Ⅱ) Sulfophthalocyanine in Ethanol-Water

作　　者：邓桂胜[1] 

机构地区：[1]湖南师范大学化学化工学院化学系,中国长沙410081

出　　处：《湖南师范大学自然科学学报》2002年第3期59-63,共5页Journal of Natural Science of Hunan Normal University

摘　　要：报道了在含醇水介质中双核磺化酞菁铜 (Ⅱ )催化氧化α 萘酚生成聚 1 ,4亚萘醚 ,并且详细地研究了温度、底物浓度、催化剂量、乙醇 水体积比、反应时间对催化氧化α 萘酚的影响 .Naphthol was oxidized to poly 1,4 naphthalene ether by oxygen using binucleus copper(Ⅱ) sulfo phthalocyanine as catalyst in ethanol water.The factors to affect this reaction,such as temperature,the concentration of α naphthol,the amount of catalyst,the volume ratio of ethanol to water and reaction time,were studied.A possible reaction mechanism was proposed.

关 键 词：含水介质 双核磺化酞菁铜 催化氧气 Α-萘酚 聚-1 4-萘醚 反应机理 催化剂 反应温度 

分 类 号：O625.313[理学—有机化学] O621.251[理学—化学]