Asymmetric nitroolefination reaction of α-substituted lactones  

作　　者：王锐 杨晓武 倪京满 

机构地区：[1]Department of Biology [2]Department of Chemistry, State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, China)

出　　处：《Progress in Natural Science:Materials International》1998年第2期111-115,共5页自然科学进展·国际材料（英文版）

基　　金：Proiect supported by the National Natural Science Foundation of China, Fok Ying Tung (Hong Kong) Education Foundation;the Doctoral Program from the State Education Commission of China.

摘　　要：Many biologically active complex natural products (e. g. terpenoids, steroids and alkaloids)possess asymmetric quaternary carbon centers. The construction of these asymmetric carbon cen-ters in enantioselective form has been a stimulating subject for organic chemists. Among the methods reported so far, the reaction of construction of nitroolefinic lactones containing asym-metric quaternary carbon centers seems to be promising, because this type of compounds can

关 键 词：ASYMMETRIC QUATERNARY carbon center chiral nitroenamine α-nitroolefinic LACTONE ASYMMETRIC syn-thesis. 

分 类 号：N[自然科学总论]