卟啉化合物的研究——四苯骈卟啉与铜、钴配位反应及其波谱学研究  

Study on Porphyrin Compounds --Study on the Coordinate Reaction and Spectroscopy in the Tetrabenzoporphine with Cu~ 2+ and Co^2+

作　　者：王林[1] 宋仲容[1] 李忠彬[1] 

机构地区：[1]渝西学院化学系,重庆永川402168

出　　处：《西南师范大学学报（自然科学版）》2002年第5期742-745,共4页Journal of Southwest China Normal University(Natural Science Edition)

摘　　要：用光度法测定了四苯骈卟啉与Cu2 + ,Co2 + 配位反应速率常数、活化能及热力学参数 .实验表明 :H2 TBP与Cu2 + ,Co2 + 配位反应速度均快 ,△H <0 ,研究了反应前后体系的吸收光谱变化 ,以及CuTBP的ESR谱 .The constant of action, activationenergy and some thermodynamic parameters on the coordinate reaction of letrabenzoporphine with Cu 2+ and Co 2+ were determimed by spectrometric methods. Experimental results had shown that the rate of coordinate reaction on Cu\+\{2+\} and Co\+\{2+\} with H\-2TBP(Δ H<0 ) was rapid.UV VIS spectra on CuTBP and Co TBP and ESR on CuTBP were reported.

关 键 词：卟啉化合物 波谱学 铜 钴 四苯骈卟啉 配位反应 电子吸收光谱 电子顺磁共振波谱 反应速率 活化能 

分 类 号：O626.13[理学—有机化学] O641.4[理学—化学]