非除氧条件下6-溴萘硫酸钾超分子组合室温燐光  

Supramolecule Assembly Room Temperature Phosphorescence of Potassium 6-bromo-2-naphthylsulfate Under Non-deoxygenation

作　　者：张海容[1] 晋卫军[2] 刘长松[2] 

机构地区：[1]山西省忻州师范学院,忻州034000 [2]山西大学化学系,太原030006

出　　处：《分析化学》2002年第10期1183-1186,共4页Chinese Journal of Analytical Chemistry

基　　金：国家自然科学基金 (No .2 9875 0 16);忻州师范学院科研基金资助项目

摘　　要：极少量环己烷存在下 ,由于超分子化合物 β CD BNS 环己烷的形成 ,不经除氧可观察到强的室温光(RTP)发射。同时 ,对影响超分子化合物发光性质的各种因素如形成三元包合物、空间匹配效应。The strong room temperature phosphorescence(RTP) emission was observed from supramolecular species β cyclodextrin/6 bromo 2 naphthylsulfate/cyclohexane without removing dissolved oxygen from solution in the presence of micro amounts of cyclohexane. At the same time, the effect of various factors on the luminescent properties of supramolecular compounds such as forming ternary complex, the effect of space matching and the structure of guest molecules as well as the interaction of different alcohols with other components in the ternary complex system were studied in detail.

关 键 词：非除氧条件 6-溴萘硫酸钾 超分子化学 环己烷 室温Lin光 环糊精 光谱分析 RTP发射 

分 类 号：O657.3[理学—分析化学] O641.3[理学—化学]