某些仲胺配位体的合成  

Synthesis of some secondary amine ligands

作　　者：刘长畿[1] 

机构地区：[1]中国科学院上海有机化学研究所

出　　处：《化学试剂》1989年第6期369-371,共3页Chemical Reagents

摘　　要：用β-支链醇、仲醇、氯代十二烯及环氧乙烷烷基化仲碳伯胺,合成了8个仲胺配位体。为此目的专门制备了铜镍型催化剂。这些仲胺化合物可用于稀有元素的分离。Eight secondary amine ligands were synthe-sized by alkylation of primary amine carried a se-condary carbon atom with β-branched chain alco-hols,secondary alcohols,dodecenyl chloride andepoxide ethylene.For this purpose,catalyst ofCu-Ni type were prepared specifically.Thesesecondary amine-ligands possibly are usefulin the separation of rare elements.

关 键 词：仲胺 配位体 合成 稀有元素 

分 类 号：O623.731[理学—有机化学]