丙氨酸咪唑钐的三维荧光激发和发射光谱  

THREE-DIMENSION FLUORESCENCE EXCITATION AND EMISSION SPECTRUM OF ALANINE IMIDAZOLE SM COMPOUND

作　　者：杨一心[1] 赵天成[2] 白晋涛[3] 张秀成[2] 陈慰宗[4] 李绍雄[4] 

机构地区：[1]西北大学化学系/陕西省物理无机化学重点实验室,西安710069 [2]西北大学化学工程系,西安710069 [3]西北大学光子学与光子技术研究所,西北大学光电子技术省级重点开放实验室,西安710069 [4]西北大学物理学系,西安710069

出　　处：《光子学报》2002年第9期1165-1168,共4页Acta Photonica Sinica

基　　金：陕西省科技攻关项目 (2 0 0 1K0 8-G5 ) ;陕西省自然科学基金 (97H0 4) ;陕西省教育厅重点科技项目 (99JK1 0 );陕西省教育厅专项基金 (0 0JK1 2 0 )资助项目

摘　　要：测量了新制丙氨酸咪唑钐水溶液的三维荧光激发和发射光谱 ,分析了在不同波长激发光作用下的荧光特征 ,与配体咪唑、α 丙氨酸及氯化钐的荧光谱进行了比较 ,讨论了模型化合物上转换荧光中的双光子和多光子加合现象并发现在 1 0 - 2 - 1 0 - 4The three dimension fluorescence excitation and emission spectrum of the aqueous solution of alanine imidazole Sm has been first measured,the compound′s fluorescence property with different wavelength excitation light was analysised,writer also compared its fluorescence spectrum with imidazole,α alanine and SmCl 3′s ,the additive phenomenon of double light and multi light in the up conversion fluorescence of heading compound was discussed. The range of its concentration between 10 -2 ～10 -4 mol/L,writer found that the fluorescence intensity of the compound is proportional to its concentration.

关 键 词：丙氨酸咪唑钐 三维荧光激发 发射光谱 升频转换荧光 发光性能 稀土有机络合物 

分 类 号：O614.337[理学—无机化学] O657.3[理学—化学]