互穿交联网络结构内养护材料St/AM/AMPS-TEOS的制备  

Preparation of internal curing material St/AM/AMPS-TEOS for interpenetrating crosslinked network structure

作　　者：周睿哲[1] 刘荣进[1,2] 陈平[1,2] 邓洪宇[1] Zhou Ruizhe;Liu Rongjin;Chen Ping;Deng Hongyu(College of Materials Science and Engineering, Guilin University of Technology, Guilin 541004, China;Ministry-Province Jointly-Constructed Cultivation Base for State Key Laboratory of Processing for Non-Ferrous Metal and Featured Materials, Guilin 541004, China)

机构地区：[1]桂林理工大学材料科学与工程学院,广西省桂林市541004 [2]广西有色金属及特色材料加工国家重点实验室培育基地,广西省桂林市541004

出　　处：《合成树脂及塑料》2016年第6期17-22,共6页China Synthetic Resin and Plastics

基　　金：国家自然科学基金(51202039);广西自然科学基金(2014GXNSFAA118314);广西科学研究与技术开发计划(桂科攻1348011-2);江西省重点新产品计划(20113CX19900);广西校地校企科技创新平台建设项目

摘　　要：采用自由基溶液聚合法配合互穿网络技术，以淀粉（St）、丙烯酰胺（AM）、2-丙烯酰胺基-2-甲基丙磺酸（AMPS）、正硅酸乙酯（TEOS）为主要原料，合成了St/AM/AMPS-TEOS聚合物内养护材料。扫描电子显微镜分析及能谱元素分析结果表明，AM，AMPS已经成功接枝到淀粉主链，所得内养护材料具有互穿交联网络结构特征。该材料合成反应的最佳条件为：w（TEOS）为5.5%~7.5%，交联剂N,N-亚甲基双丙烯酰胺质量分数为0.25%，反应温度70~72℃，溶液pH值1.0~1.5，反应时间20~30min。所得内养护材料吸水率达253.68%，释水率达91.76%。The internal curing material St-AM-AMPS-TEOS was synthesized by use of free radical solution polymerization coupled with interpenetrating network(IPN) technology as well as with starch(St),acrylamide(AM), 2-acrylamido-2-methylpropane sulfonic acid(AMPS), and tetraethoxysilane(TEOS)as raw materials. The results of scanning electron microscope(SEM) and elemental diffraction spectrum (EDS)show that AM and AMPS have successfully grafted to the main chain of the starch, the internal curing material obtained features interpenetrating crosslinked network structure. The optimal conditions for the synthesis of the material are as follows: dosage of TEOS is 5.5%-7.5%, mass fraction of crosslinking agent is 0.25%, pH value of solution is 1.0-1.5, reaction temperature is between 70 to 72 ℃, and reaction time is from 20 to 30 minutes.The water absorbency of the internal curing material is 253.68 g/g and its water releasing ratio is 91.76%.

关 键 词：内养护材料 合成 互穿网络 正硅酸乙酯 

分 类 号：TU528[建筑科学—建筑技术科学]