丙烯酸酯接枝改性天然橡胶增韧聚乳酸  

Toughening of Polylactide with Acrylate Grafting Modified Natural Rubber

作　　者：张春梅[1] 翟天亮 罗勇悦[3] Zhang Chunmei;Zhai Tianliang;Luo Yongyue(College of Chemistry and Materials Engineering, Guiyang University, Guiyang 550005, China;Guizhou Building Material Quality Supervision Testing Center, Guiyang 550000, China;Agricultural Product Processing Research Institute, Chinese Academy of Tropical Agricultural Sciences, Zhanjiang 524001, China)

机构地区：[1]贵阳学院化学与材料工程学院,贵阳550005 [2]贵州省建材产品质量监督检验院,贵阳550000 [3]中国热带农业科学院农产品加工研究所,广东湛江524001

出　　处：《工程塑料应用》2017年第10期19-23,39,共6页Engineering Plastics Application

基　　金：贵州省普通高等学校科技拔尖人才支持计划(黔教合KY字[2016]089);贵州省科学技术基金项目(黔科合J字[2015]2006号);国家质量监督检验检疫总局科技计划项目(2016QK041)

摘　　要：通过在天然橡胶(NR)分子链上接枝甲基丙烯酸甲酯(MMA)和丙烯酸丁酯(BA),制备了三种丙烯酸酯接枝改性NR:NR-g-PMMA,NR-g-PBA和NR-g-(PMMA,PBA)。采用核磁共振氢谱对三种接枝物进行了化学结构鉴定。将接枝改性后的NR和未改性的NR与PLA采用哈克密炼机熔融共混,分别制备了PLA/NR,PLA/NR-gPMMA,PLA/NR-g-PBA和PLA/NR-g-(PMMA,PBA)共混物,研究了接枝改性NR和未改性NR含量对共混物力学性能和热性能的影响。各共混物的拉伸弹性模量和拉伸强度均随接枝改性NR和未改性NR含量的增加而降低,断裂伸长率和缺口冲击强度随接枝改性NR和未改性NR含量的增加而提高。其中,PLA/NR-g-PBA共混物的断裂伸长率和缺口冲击强度比其它共混物提高的幅度大,当NR-g-PBA的质量分数为5%时,PLA/NR-g-PBA共混物的断裂伸长率达到78%,缺口冲击强度为5.2 k J/m2,而纯PLA的断裂伸长率仅为7.7%,缺口冲击强度为2.5 k J/m2,说明NR接枝分子柔顺性较高的BA更有利于促进其与PLA共混物的韧性提高。热分析结果表明,PLA/NR-gPBA共混物的热稳定性相比于纯PLA也有所提高。By grafting of natural rubber(NR)with methyl methacrylate(MMA)and butyl acrylate(BA),three kinds of acrylate grafting modified NR:NR-g-PMMA,NR-g-PBA and NR-g-(PMMA,PBA)were prepared.The chemical structures were characterized by hydrogen nuclear magnetic spectra.Polylactide(PLA)/NR,PLA/NR-g-PMMA,PLA/NR-g-PBA and PLA/NR-g-(PMMA,PBA)blends were prepared by melt blending grafting modified NR and unmodified NR with PLA respectively in a Haake internal melt mixer.The mechanical and thermal properties of the blends were investigated as a function of grafting modified NR and unmodified NR content.The tensile modulus of elasticity and tensile strength of the blends decrease with the increase of grafting modified NR and unmodified NR content,but the elongation at break and notched impact strength increase.Among them,the PLA/NR-g-PBA blend shows a higher increasing range in elongation at break and notched impact strength than other blends,when5%NR-g-PBA is introduced,the elongation at break and notched impact strength of PLA/NR-g-PBA blend is78%and5.2kJ/m2,however,pure PLA shows a7.7%of elongation at break and2.5kJ/m2of notched impact strength,respectively.Which indicating that by grafting of NR with a flexible polymer like PBA is more beneficial to promoting the toughness of the blend with PLA.The thermal analysis results show that the thermal stability of PLA/NR-g-PBA blend is also improved compared to that of pure PLA.

关 键 词：聚乳酸 天然橡胶 接枝改性 丙烯酸酯 增韧 

分 类 号：TB324[一般工业技术—材料科学与工程]