环保型气相防锈剂的研制  

Preparation of environment-friendly vapor phase inhibitor

作　　者：张恒 张天 ZHANG Heng;ZHANG Tian(College of Marine Science and Biological Engineering,Qingdao University of Science&Technology,Qingdao,Shandong 266042,China;Guangxi Key Laboratory of Clean Pulp&Papermaking and Pollution Control,Nanning,Guangxi 530004,China)

机构地区：[1]青岛科技大学海洋科学与生物工程学院,山东青岛266042 [2]广西清洁化制浆造纸与污染控制重点实验室,广西南宁530004

出　　处：《河北工业科技》2018年第2期117-122,共6页Hebei Journal of Industrial Science and Technology

基　　金：山东省自然科学基金(ZR2017MC032);广西清洁化制浆造纸与污染控制重点实验室开放基金(KF201715)

摘　　要：安全、无毒、环保是气相防锈剂的发展趋势。为了对国内以亚硝酸钠为主要成分的气相防锈剂进行更新换代,研究制备了环保型气相防锈剂。采用静态吊片法和动态盐雾试验,对苯甲酸钠、苯并三氮唑、乌洛托品、碳酸环己胺4种物质进行缓蚀研究,通过单组分及多组分复配进行静态防锈甄别实验,研究了苯甲酸钠、乌洛托品、苯并三氮唑和碳酸环己胺在5%(质量分数)NaCl氛围中对Q235型钢片腐蚀行为的影响。实验结果表明:优选配方以苯甲酸钠为主要原料,m(苯甲酸钠)∶m(乌洛托品)∶m(苯并三氮唑)∶m(碳酸环己胺)=5∶2∶2∶1;经盐雾试验对配方的防锈效果进行验证,发现当其以薄膜形式使用时,试样在15d后仍保持光亮无锈。此气相防锈剂不仅安全高效,而且低毒环保,具有协同增效作用,可作为对以亚硝酸钠为主要成分的气相防锈剂的更新换代产品。Being safe,non-toxic,environmental protection is the development trend of vapor phase inhibitor.In order to update and replace the vapor phase inhibitor with sodium nitrite as the main component in China,the environmental protection inhibitor is prepared.The corrosion inhibition of sodium benzoate,1H-benzotriazole,hexamethylenetetramine,and cyclohexylamine carbonate is studied by static suspension method and dynamic salt spray test.The static antirust screening experiments are carried out with a single component and multi component.The effect of sodium benzoate,hexamethylenetetramine,1H-benzotriazoleand cyclohexylamine carbonate on corrosion behavior of Q235 steel sheet is studied in 5%(mass fraction)NaCl atmosphere.The experimental results show that the preferred formula of m(sodium benzoate)∶m(hexamethylenetetramine)∶m(1H-benzotriazole)∶m(cyclohexylamine carbonate)is 5∶2∶2∶1.The antirust effect of the formula is verified by the neutral salt spray test,and the sample remains bright and rustless after 15 d when it is used in the form of antirust film.This vapor phase inhibitor is safe and efficient with low toxicity and environmental protection,and it has synergistic effect,so it can be used for replacing the vapor phase inhibitor with sodium nitrite as the main component.

关 键 词：黑色金属及其合金 气相防锈剂 复配 缓蚀 盐雾试验 

分 类 号：TQ174.42[化学工程—陶瓷工业]