龙涎香香原料卷烟应用及降龙涎醚的合成研究进展  

The Application of Ambergris Flavor in Tobacco Industry and Development of Synthesis of(-)-Ambrox

作　　者：王耀 陶飞燕 周志刚 罗诚 徐恒 WANG Yao;TAO Fei-yan;ZHOU Zhi-gang;LUO Cheng;XU Heng(China Tobacco Sichuan Industrial Co.LTD,Chengdu 610066,China)

机构地区：[1]四川中烟工业有限责任公司,四川成都610066

出　　处：《合成化学》2018年第1期55-65,共11页Chinese Journal of Synthetic Chemistry

基　　金：中国烟草总公司重点项目(110201402035)

摘　　要：介绍了龙涎香的组成及龙涎香香原料在卷烟工业中的应用,并从半合成的角度对降龙涎香醚的合成进行了综述。降龙涎香醚的合成主要以具有类似结构的植物提取物香紫苏醇为原料,重点阐述了合成过程中的重要中间体及副产物的生成,并详细介绍了反应机理。The composition and application of ambergris products in tobacco industry were briefly introduced with 44 references.The synthesis of(-)-ambrox was also reviewed.The development of synthesis of(-)-Ambrox using sclareol from Salvia SclareL.extracts as raw material was described and the reaction mechanism was discussed by analyzing the key intermediates and by-products.

关 键 词：烟用香精 香紫苏醇 香紫苏内酯 降龙涎二醇 降龙涎香醚 合成 综述 

分 类 号：O621.3[理学—有机化学]