儿茶酚硼烷及其衍生物在有机反应中的应用进展  

Progress of the Application of Catecholborane and its Derivatives in Organic Reaction

作　　者：姜涛 王合营 许芳 崔崑[2] 马志[2] JIANG Tao;WANG Heying;XU Fang;CUI Kun;MA Zhi(College of Chemical Engineering and Materials Science,Tianjin University of Science&Technology,Tianjin 300457,China;Shanghai Institute of Organic Chemistry,Chinese Academy of Sciences,Shanghai 200032,China)

机构地区：[1]天津科技大学化工与材料学院,天津300457 [2]中国科学院上海有机化学研究所,上海200032

出　　处：《天津科技大学学报》2018年第2期1-12,19,共13页Journal of Tianjin University of Science & Technology

基　　金：国家自然科学基金资助项目(21374130)

摘　　要：儿茶酚硼烷具有制备方法简单、性质稳定、易贮存、与烯烃和炔烃在温和的条件下反应速率快、区域选择性和立体选择性高、易于功能化和自由基化等特点,因而在硼氢化反应和还原反应等方面得到了广泛的应用.本文首先简述了儿茶酚硼烷的合成方法和性质,然后对近年来儿茶酚硼烷及其衍生物在硼氢化反应、还原反应、脱氧反应以及自由基反应等有机反应中的应用研究新进展进行详细的评述,最后对儿茶酚硼烷及其衍生物在有机反应中的应用前景进行了展望.Catecholborane(HBcat)can be prepared with several methods.It is stable,easy for storage,and can react with olefins and alkynes quickly under mild conditions.During the hydroboration process,it not only shows the characteristics of high selectivity and stereoselectivity,but also functionalizes and radicalizes easily,so it has been widely used in hydroboration and reduction reactions.In this paper,the synthesis methods and properties of catecholborane were briefly summarized,and the application of catecholborane and its derivatives in hydroboration,reduction,deoxygenation and free radical reaction are detailedly introduced.The prospect of catecholborane and its derivatives in organic reaction are also discussed.

关 键 词：儿茶酚硼烷 硼氢化反应 还原反应 自由基反应 

分 类 号：O632.1[理学—高分子化学] O631.5[理学—化学]