磺化聚醚砜/聚醚砜共混膜催化酯化反应性能研究  

Study on catalytic esterification of sulfonated polyethersulfone and polyethersulfone blend membrane

作　　者：石文英[1,2] 李红宾[1,2] 刘永昌 SHI Wen-ying;LI Hong-bin;LIU Yong-chang(School of Textiles Engineering,Henan University of Engineering,Zhengzhou 450007,China;Henan Engineering Laboratory of New Textiles Development,Henan University of Engineering,Zhengzhou 450007,China)

机构地区：[1]河南工程学院纺织学院,河南郑州450007 [2]河南工程学院纺织新产品开发河南省工程实验室,河南郑州450007

出　　处：《应用化工》2018年第8期1641-1644,共4页Applied Chemical Industry

基　　金：国家自然基金资助项目(51403052);河南省高等学校青年骨干教师培养计划(2017GGJS151);河南省高等学校重点科研项目(16A480005)

摘　　要：制备了磺化聚醚砜SPES膜和3种磺化度的SPES/PES共混膜用于催化酯化酸化油制备生物柴油。考察了磺化度、催化膜用量、酸化油和甲醇质量比、反应时间对酯化反应的影响。结果表明,单独使用SPES催化膜较脆,而SPES/PES共混膜机械强度较好,其中磺化度20.3%SPES/PES膜的重复使用性能最好。SPES/PES共混膜催化酯化酸化油制备生物柴油的最佳反应条件为:磺化度20.3%的SPES/PES共混膜为催化剂,催化膜用量1.66%,醇油质量比为1∶1,反应温度65℃,反应时间6 h,此时酸化油转化率为97.44%。Sulfonated polyethersulfone(SPES)membranes and three kinds of SPES/PES blend membranes with three sulfonated degree were prepared for catalytic esterification of acidified oil for biodiesel production.The effects of sulfonation degree,amount of catalytic membranes,mass ratio of acidified oil to methanol and reaction time on esterification reaction were investigated.The results showed that the SPES membrane was more brittle and the mechanical strength of the SPES/PES blend membrane was better,and the reusability of the sulfonated 20.3%SPES/PES membrane was the best.The optimum reaction conditions for the preparation of biodiesel from the SPES/PES blend membrane catalyzed by the acidified oil were as follows:the SPES/PES blend membrane with 20.3%sulfonated degree as the catalyst,the amount of the catalytic film of 1.66%,the mass ratio of the alcohol oil of 1∶1,the reaction temperature of 65℃,the reaction time of 6 h,and the conversion of acidified oil is 97.44%.

关 键 词：生物柴油 酸化油 共混膜 磺化聚醚砜 催化酯化 

分 类 号：TQ645[化学工程—精细化工] TE667[石油与天然气工程—油气加工工程]