基于吡咯的阴离子受体研究进展  

Progress in pyrrole-based anion receptors

作　　者：熊晓莉[1] XIONG Xiao-li(National Experimental Teaching Demonstration Center of Environmental and Resource Chemical Technology, Chongqing Technology and Business University,Chongqing 400067,China)

机构地区：[1]重庆工商大学环境与资源化学技术国家级实验教学示范中心,重庆400067

出　　处：《应用化工》2018年第8期1736-1740,共5页Applied Chemical Industry

基　　金：国家自然科学基金(20907076);重庆市科学技术委员会基础科学与前沿技术研究(cstc2016jcyj A2300);中央财政支持地方高效改革发展专项资金资助<环境与能源催化创新团队建设项目>(渝财教(2017)91号680217007)

摘　　要：识别阴离子的超分子体系作为一个新的研究领域,在传感器、萃取剂、阴离子响应性材料、离子载体及其它领域得到了迅速发展。综述了单吡咯受体、基于二吡咯烯和二吡咯酮的受体以及联吡咯甲烷受体等非环吡咯体系在阴离子识别方面的应用。非环吡咯比环状吡咯化合物更容易合成,因此非环吡咯衍生物将作为构筑单元被广泛用于创造更复杂的阴离子受体。The use of supramolecular systems capable of recognition anions is a novel area that has rapidly evolved into the development of sensors,extractants,anion-responsive materials,and anion carriers,among other application areas.This article reviews the applications of acyclic pyrrole systems,such as monomeric pyrrole receptors,dipyrrin and dipyrrinone receptors,dipyrromethane receptors,in anion recognition.Being easier to synthesize than their macrocyclic congeners,acyclic pyrrole derivatives will be widely used as building blocks for the creation of more complex receptors.

关 键 词：阴离子识别 吡咯 超分子 进展 

分 类 号：TQ42[化学工程] TQ2