Y^(3+)和Gd^(3+)对LaBO_3:Eu^(3+)发光粉结构和发光性能的影响  

Effects of Y^(3+) and Gd^(3+) Ions on Structure and Luminescence Properties of LaBO_3:Eu^(3+) Phosphors

作　　者：马晶 赵婉男 李艳红 MA Jing;ZHAO Wan-nan;LI Yan-hong(School of Material Science and Engineering,Shenyang University of Chemical Technology,Shenyang 110142,China;China Zhenhua(Group)Xinyun Electronic Comp.&Dev.Co.,Ltd.,Guiyang 550018,China)

机构地区：[1]沈阳化工大学材料科学与工程学院,辽宁沈阳110142 [2]中国振华(集团)新云电子元器件有限责任公司,贵州贵阳550018

出　　处：《发光学报》2018年第9期1213-1219,共7页Chinese Journal of Luminescence

基　　金：辽宁省教育厅科学技术研究项目(L2011063)资助~~

摘　　要：采用溶胶凝胶-燃烧法合成了系列不同掺杂浓度Y^(3+)和Gd^(3+)的LaBO_3:Eu^(3+)发光粉,对其结构、形貌和发光性能进行了表征。XRD研究结果表明:发光粉的结构与基质掺杂离子的种类和掺杂浓度有关系。荧光光谱结果表明:适量比例Y^(3+)和Gd^(3+)离子掺杂将提高LaBO_3:Eu^(3+)发光粉的发光强度。Y^(3+)和Gd^(3+)离子最佳掺杂摩尔分数分别为1.5%和12.5%。5D0→7F2与5D0→7F1跃迁发射的相对强度比值说明:掺杂改变LaBO_3:Eu^(3+)中Eu^(3+)局域环境的对称性。发光性能改变主要受晶体结构、掺杂离子电负性影响。Gd^(3+)离子掺杂更有利于发光粉结构稳定性和发光性能的改善。A series of LaBO 3∶Eu 3+phosphors with Y 3+and Gd 3+ions different doping concentrations were prepared by sol-gel combustion method.The structure,morphology and luminescence are characterized.The results of XRD indicate that the structures of phosphors are related to doping ions and doping concentration of matrix.The results of emission and excitation spectra show that the luminescence intensity of LaBO 3∶Eu 3+phosphors is enhanced by appropriate proportion Y 3+and Gd 3+ions doping in hosts.Y 3+and Gd 3+optimum doping mole fraction is 1.5%and 12.5%,respectively.The 5D 0→7F 2/5D 0→7F 1 relative emission intensity ratios show that the local symmetry environment around Eu 3+ions is changed because of doping ions.The luminescence properties are influenced by the crystal structure and electronegativity of doping ion.In addition,the Gd 3+doping is more advantageous to the stability of structure and improvement of luminescence properties.

关 键 词：溶胶-凝胶燃烧法 LaBO3∶Eu^3+ 发光粉 发光性能 

分 类 号：O482.31[理学—固体物理] TQ133.3[理学—物理]