葡萄糖制备5-羟甲基糠醛工艺研究  

Preparation of 5-hydroxymethylfurfural from glucose

作　　者：罗应[1] 李彦青 柏文俊 程昊 黄文艺 孔红星 LUO Ying;LI Yan-qing;BO Wen-jun;CHENG Hao;HUANG Wen-yi;KONG Hong-xing(Lushan College of Guangxi University of Science and Technology,Liuzhou 545616,China;College of Biological and Chemical Engineering,Guangxi Key Laboratory of Green Processing of Sugar Resources,Key Laboratory for Processing of Sugar Resources of Guangxi Higher Education Institutes,Guangxi University of Science and Technology,Liuzhou 545006,China)

机构地区：[1]广西科技大学鹿山学院,广西柳州545616 [2]广西科技大学生物与化学工程学院广西糖资源绿色加工重点实验室广西高校糖资源加工重点实验室,广西柳州545006

出　　处：《应用化工》2018年第9期1884-1887,1891,共5页Applied Chemical Industry

基　　金：广西教育厅科研项目资助(KY2015YB170);广西糖资源绿色加工重点实验室;广西高校糖资源加工重点实验室开放基金资助(2016TZYKF02)

摘　　要：为实现5-羟甲基糠醛绿色化、低成本制备,以可再生资源葡萄糖为原料,固体酸为催化剂,在水-γ-戊内酯双相介质中经酸化水解制备出5-羟甲基糠醛。考察了反应温度、反应时间、催化剂用量、葡萄糖用量对5-羟甲基糠醛收率的影响。结果表明,最佳工艺条件:反应温度190℃,反应时间43 min,催化剂用量0. 3 g,葡萄糖用量0. 15 g,在此条件下,5-羟甲基糠醛的收率44. 7%。Glucose as a renewable resource was adopted to prepare 5-hydroxymethyl furfural(5-HMF)in the presence of solid acid catalyst,which was green and low-cost,and 5-HMF was successfully obtained by hydrolysis acidification in a biphase water/γ-valerolactone medium.The influences of reaction temperature,reaction time,catalyst dosage and amount of glucose were examined.The result showed that the optimum process conditions were determined as follows:reaction temperature 190℃,reaction time 43 min,amount of catalyst 0.3 g and dosage of glucose 0.15 g.Under these conditions,the yield of 5-HMF was 44.7%.

关 键 词：5-羟甲基糠醛 葡萄糖 固体酸催化剂 响应面法 

分 类 号：TQ23[化学工程—有机化工] O626[理学—有机化学]