多碘含能反生物战剂合成研究进展  

Research Progress in Iodine-based Energetic Biocidal Agents

作　　者：陈鹏[1,2] 窦辉 费腾 何春林[1,2] 庞思平 CHEN Peng;DOU Hui;FEI Teng;HE Chun-lin;PANG Si-ping(State Key Laboratory of Explosion Science and Technology,Beijing Institute of Technology,Beijing 100081,China;School of Materials science&Engineering,Beijing Institute of Technology,Beijing 100081,China)

机构地区：[1]北京理工大学爆炸科学与技术国家重点实验室,北京100081 [2]北京理工大学材料学院,北京100081

出　　处：《含能材料》2018年第11期958-966,共9页Chinese Journal of Energetic Materials

基　　金：爆炸科学与技术国家重点实验室基金(QNKT18-03);国家自然科学基金资助(21702017;21576026)

摘　　要：传统含能化合物在爆炸后产生的瞬间热效应无法有效杀灭生物武器所携带的生物战剂。多碘含能反生物战剂化合物在爆炸后可以同时释放出能量和杀菌剂,因此,其被认为是当前最有应用前景的含能反生物战剂化合物。系统综述了共价型、离子型和共晶型三类多碘含能反生物战剂化合物的合成和性能研究进展,并介绍了部分反生物战剂的杀菌效果。结合含能反生物战剂的构效关系,指出热稳定性好,密度高,碘含量高,杀菌效果好的新型多碘含能反生物战剂化合物是今后的研究重点。此外,在保证杀菌效果良好的前提下,不断提升反生物战剂的能量密度和抛洒范围是当前反生物战剂研究发展的趋势。The instantaneous thermal effect from the explosion of traditional explosives cannot effectively kill biological agents carried by biological weapons.Iodine-rich compounds can not only release energy,but also efficiently kill biological agents.Therefore,iodine-rich compounds has been thought as the most promising“energetic biocidal agent”compounds.This paper reviews the synthesis and properties of covalent,ionic and co-crystal iodine-rich compounds,and presents bactericidal ability of part“energetic biocidal agent”compounds.Combined with the structure-function relationship,this review points out that developing new iodine-richcompounds with good thermostability,high density,high iodine and high bactericidal activity,will be a research focus on“energetic biocidal agent”compounds.Moreover,on the premise of good bactericidal ability,constantly increasing the energy density and spraying range of“energetic biocidal agent”compounds is another development trend of anti-biological agent research.

关 键 词：反生物战剂 设计与合成 高碘化合物 

分 类 号：TJ55[兵器科学与技术—军事化学与烟火技术] TQ56[化学工程—炸药化工]