含Co配合物的ZnO纳米棒复合材料光电化学性质  

Photoelectrochemical Properties for Composite Material ZnO Nanorods with Co Complex

作　　者：齐悦 杨洁 QI Yue;YANG Jie(Experiment Teaching Center of Basic Chemistry,Sichuan University,Chengdu 610064,China;College of Chemistry,Sichuan University,Chengdu 610064,China)

机构地区：[1]四川大学基础化学实验教学中心,成都610064 [2]四川大学化学学院,成都610064

出　　处：《实验室研究与探索》2018年第10期21-23,共3页Research and Exploration In Laboratory

基　　金：国家自然科学基金项目(51502181)

摘　　要：在氧化铟锡(Indium Tin Oxide,ITO)玻璃上制备ZnO纳米棒,并采用一种简单的自组装方法在含有ZnO纳米棒的ITO玻璃上制备Co(2. 6-NDC)(4,4'-Bipy)0. 5配合物。实验表明,含Co配合物并没有和ZnO纳米棒发生反应,而是比较均匀地沉积在ZnO纳米棒上。在光电化学实验中,做了仅有ZnO和含Co配合物的ZnO纳米棒的线性伏安法测试对比实验,证明含Co配合物起到了良好的催化能力。说明这种简单的自组装方法制备的金属氧化物半导体和MOFs组成的复合材料在光电化学中具有潜在的应用价值。A facile method has been developed to fabricate the complex of Co(2.6-NDC)(4,4′-Bipy)0.5 using indium tin oxide glass(ITO)coated with ZnO nanorods as the substrate.Co(2.6-NDC)(4,4′-Bipy)0.5 complex does not have any chemical reaction with ZnO nanorods.Instead,the complex coats on the surface of ZnO nanorods homogeneously as indicated by SEM results.The results of linear sweep voltammetry suggest Co(2.6-NDC)(4,4′-Bipy)0.5 complex exhibits the superior catalytic property compared with ZnO nanorods.The composite of metal oxide semiconductor and MOFs prepared by such facial method may have the potential application in the photoelectrochemistry.

关 键 词：金属有机框架 纳米棒 光电化学 复合材料 线性伏安法 

分 类 号：O611.6[理学—无机化学] TB34[理学—化学]