(1,5-环辛二烯)氯化钌(Ⅱ)多聚体的合成及表征  

Synthesis and Characterization of Dichloro(1,5-cyclooctadiene)ruthenium(Ⅱ) Polymer

作　　者：晏廷玺 赵婧[2] 李杰[2] 刘伟平[2] 晏彩先[2] YAN Tingxi;ZHAO Jing;LI Jie;LIU Weiping;YAN Caixian(Yunnan Tin Co.Ltd.,Datun Tin Mine,Honghe 661021,Yunnan,China;Kunming Institute of Precious Metals,State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals,Sino-Platinum Metals Co.Ltd.,Kunming 650106,China)

机构地区：[1]云南锡业股份公司大屯锡矿,云南红河661021 [2]昆明贵金属研究所,贵研铂业股份有限公司稀贵金属综合利用新技术国家重点实验室,昆明650106

出　　处：《贵金属》2018年第A01期113-116,共4页Precious Metals

基　　金：云南省基础研究计划项目(2017FD212,2017FB141);云南省省院省校科技合作项目(2015IB019)。

摘　　要：在无水乙醇介质中,将水合三氯化钌与1,5-环辛二烯加热回流,一步合成了(1,5-环辛二烯)氯化钌(Ⅱ)多聚体[Ru(cod)Cl2]n,产率96%。用元素分析、核磁共振(1H-NMR、13C-NMR)和红外光谱(IR)等分析表明产物为目标化合物。[Ru(cod)Cl2]n was synthesized in one-step process from RuCl3·3H2O in alcohol by adding 1,5-cyclooctadiene as the anion ligand.The yield was 96%.Structure of the complexes have been represented by the structural analytical methods like elemental analysis,1H-NMR,13C-NMR,IR,then their chemical construction were confirmed finally.

关 键 词：(1 5-环辛二烯)氯化钌(II)多聚体 合成 表征 

分 类 号：O627.8[理学—有机化学]