4,4’-二氨基二环己基甲烷缩邻香草醛镱配合物的合成及近红外发光性能研究  

Structure and NIR Luminescene of N,N'-Bis(2-hydroxy-3-methoxybenzylidene)-4,4'-diamino Dicyclohexyl Methane Ytterbium Lanthanide Complex

作　　者：司为丹 朱文萍 杨智博 陈楚婷 王广州 栾芳 SI Wei-dan;Zhu Wen-ping;YANG Zhi-bo;CHEN Chu-ting;WANG Guang-zhou;LUAN Fang(Department of chemistry, college of pharmacy, Jiamusi university, Heilongjiang Jiamusi 154007)

机构地区：[1]佳木斯大学药学院化学系,黑龙江佳木斯154007

出　　处：《佳木斯大学学报（自然科学版）》2018年第6期933-936,共4页Journal of Jiamusi University：Natural Science Edition

基　　金：黑龙江省大学生创新创业训练计划项目(201710222066);黑龙江省教育厅基础研究项目(2016-KYYWF-0568)

摘　　要：采用常规方法合成双Schiff碱配体4,4’-二氨基二环己基甲烷缩邻香草醛,再与Yb(ClO4)3·9H2O以溶剂扩散法合成稀土配合物。分别对双Schiff碱配体及镱配合物进行紫外光谱、红外光谱、核磁共振氢谱表征及近红外光谱分析。实验结果表明,成功合成了4,4’-二氨基二环己基甲烷缩邻香草醛配体及镱配合物,镱配合物的固态近红外发光性能良好。此合成方法简便可行,为其进一步研究及应用奠定了基础。N,N’-bis(2-hydroxy-3-methoxybenzylidene)-4,4’-diamino dicyclohexyl methane ligand was synthesized by conventional method,then the ligand reacted with Yb(ClO4)3·9H2O by solvent diffusion to generate ytterbium complex.The ligand and complex were characterized by UV-vis,IR and NMR,the NIR of ytterbium complex was determined.The experimental results confirmed that the schiff ligand N,N’-bis(2-hydroxy-3-methoxybenzylidene)-4,4’-diamino dicyclohexyl methane and ytterbium complex were synthesized successfully.The complex presented better near-infrared luminescence property in solid.The method is simple and feasible,which put a good foundation for the further application and development of them.

关 键 词：4 4'-二氨基二环己基甲烷缩邻香草醛 镱配合物 合成 近红外发光 

分 类 号：O641.4[理学—物理化学]