两种以3,3′,5,5′-联苯四羧酸为配体的金属有机配位聚合物的合成、结构及发光性能  

Synthesis,Structure and Luminescence Properties of Two Metal-Organic Frameworks Coordinated by 3,3′,5,5′-Biphenyltetracarboxylic Acid

作　　者：刘颖昕[1] 刘威[1] 黄玲巧 胡雨嫣 Liu Yingxin;Liu Wei;Huang Lingqiao;Hu Yuyan(Chongqing Normal University,Chongqing 401331,China)

机构地区：[1]重庆师范大学,重庆401331

出　　处：《云南化工》2018年第10期112-113,共2页Yunnan Chemical Technology

摘　　要：使用3,3′,5,5′-联苯四羧酸(H4BPTC)为主要有机配体,2,2′-联吡啶(bipy)为辅助有机配体,分别与Co、Ni两种金属离子构建了三维金属-有机骨架结构。该两种配合物均为溶剂热的方法合成,并讨论了这两个化合物的发光性能。3,3′,5,5′-biphenyltetracarboxylic acid(H4BPTC)and 2,2′-bipyridine(bipy)was used as the main organic ligand and auxiliary organic ligand respectively,which was constructed with two metal ions,Co and Ni,to synthesize two three-dimensional metal-organic framework structure.Both complexes were synthesized by solvothermal methods and the luminescent properties of these two compounds were discussed.

关 键 词：金属有机骨架 3 3′ 5 5′-联苯四羧酸 发光 

分 类 号：O641.4[理学—物理化学] O657.2[理学—化学]