基于衣康酸酐的功能单体的合成与应用  

Synthesis and Application of Functional Monomer Based on Itaconic Anhydride

作　　者：杨小庆 刘晓倩 魏宏亮 楚晖娟 李晶晶 Yang Xiaoqing;Liu Xiaoqian;Wei Hongliang;Chu Huijuan;Li Jingjing(College of Chemistry, Chemical and Environmental Engineering, Henan University of Technology, Zhengzhou 450001, China)

机构地区：[1]河南工业大学化学化工与环境学院,河南郑州450001

出　　处：《广东化工》2018年第23期12-13,共2页Guangdong Chemical Industry

基　　金：河南省科技攻关项目(No.152102110073)

摘　　要：衣康酸酐是一种重要的衣康酸衍生物和精细化工原料,而糠胺是一种多官能团化合物,是重要的有机合成中间体。本文以衣康酸酐、糠胺为原料,简单、方便地合成了一种新型的功能单体,并通过该单体与常用的温敏性单体N-异丙基丙烯酰胺进行自由基共聚,制备了温敏性共聚物,通过红外、核磁等分析手段对合成的共聚物及单体进行了表征。Itaconic anhydride is an important derivative of itaconic acid and one of important fine chemical raw materials,while furfural amine is a multi-functional compound and one of important organic intermediate compounds.Herein,a novel functional monomer was synthesized simply and conveniently from itaconic anhydride and furfuryl amine.The thermosensitive copolymers were prepared by free radical copolymerization of the as-obtained monomer with N-isopropylacrylamide,a common monomer used for synthesizing thermosensitive copolymers.The monomer and its copolymers were characterized by IR and NMR,etc.

关 键 词：衣康酸酐 糠胺 温敏性 共聚 

分 类 号：TQ[化学工程]