单手性螺旋聚醚的合成与应用研究进展  

The Process of Synthesis and Application of Single-handed Helical Polyethers

作　　者：孙允凯[1] 王梦蝶 王小峰[1] SUN Yunkai;WANG Mengdie;WANG Xiaofeng(School of Chemistry and Chemical Engineering,University of South China,Hengyang,Hunan 421001,China)

机构地区：[1]南华大学化学化工学院,湖南衡阳421001

出　　处：《南华大学学报（自然科学版）》2018年第6期52-59,共8页Journal of University of South China：Science and Technology

基　　金：国家自然科学基金项目(11305086);湖南省自然科学基金项目(14JJ6021);大学生研究性学习和创新性实验计划资助项目(316)

摘　　要：螺旋聚合物是化学家研究的热点之一.单手性螺旋聚醚作为螺旋聚合物中的一大类,近十余年来引起人们的广泛关注.介绍在手性环氧丙烷3号位碳上引进大位阻基团,通过阴离子聚合合成单手性螺旋聚醚,并介绍其在手性识别、不对称催化等方面的应用研究.The helical-polymers is one of the hot research topics to the chemists.Single-handed helical polyether is a kind of spiral polymers,which has attracted much attention in past decade.In this review,the single-handed helical polyether with a bulky group at the3-position carbon of chiral epoxide derivatives synthesized by anionic polymerization,was introduced.On the other hand,its potential application,such as chiral recognition,asymmetric catalysis,was presented.

关 键 词：螺旋聚醚 环氧化合物 阴离子聚合 不对称催化 

分 类 号：O62[理学—有机化学]