阻燃剂对聚氯乙烯/聚酯复合材料性能的影响  

Effect of flame retardant on properties of polyvinyl chloride/polyester composites

作　　者：赵青华 毛秦岑 梅涛 牛应买 王栋 ZHAO Qinghua;MAO Qincen;MEI Tao;NIU Yingmai;WANG Dong(Material Science and Engineering Institute,Wuhan Textiles University,Wuhan,Hubei 430200,China;Hubei New Textile Material&Application Key Laboratory,Wuhan,Hubei 430200,China;College of Chemistry,Chemical Engineering and Biotechnology,Donghua University,Shanghai 201620,China)

机构地区：[1]武汉纺织大学材料科学与工程学院,湖北武汉430200 [2]湖北省纺织新材料及其应用重点实验室,湖北武汉430200 [3]东华大学化学化工与生物工程学院,上海201620

出　　处：《纺织学报》2019年第1期103-107,共5页Journal of Textile Research

基　　金：国家重点研发计划项目(2016YFC0206101)

摘　　要：为解决聚氯乙烯(PVC)/聚酯(PET)复合材料阻燃性能相对于纯聚氯乙烯、聚酯阻燃性能下降的问题,在聚氯乙烯/环己酮溶液中添加5种不同阻燃机制的阻燃剂,利用自动涂膜机将其涂覆在聚酯机织物上制备得到极限氧指数大于28%可应用于建筑领域的聚氯乙烯/聚酯复合材料。借助极限氧指数测试仪、接触角测试仪、可见光透过率测试仪对PVC/PET复合材料的性能进行表征。结果表明:主要成分为烯丙基苯并三唑的阻燃剂对PVC/PET复合材料有良好的阻燃效果,当PVC涂层中阻燃剂质量分数为10%,涂层厚度为1. 35 mm时,其透光率为5%,极限氧指数为30%,可满足建筑膜材料的使用要求。In order to solve the problem that the flame retardant performance of polyvinyl chloride(PVC)/polyester(PET)composites was lower than that of PVC and polyester.The PET fabricreinforced PVC composites with the limit oxygen index grenter 28%were prepared by adding different retardants in the PVC/cyclohexanone solution,and coating an polyester fabric.The properties of flame retardant,light transmission and self-cleaning of PVC/PET composites were evaluated by a limiting oxygen index tester,a contact angle tester and a visible light transmittance tester,respectively.The results demonstrate that flant redardant maihly contaraing allyl benzotriazole(WSA-105)has good flameretardant performance for PVC/PET composites.Moreover,the effects of different concentrations of WSA-105 and different thicknesses of PVC coating on limiting oxygen index,contact angle and light transmittance of the PVC/PET fabric composite were studied,and the results indicate that the light transmittance is 5%and the limiting oxygen index is 30% with the flame retardant concentration of 10% and the coating thickness of 1.35 mm for construction membrane materials.

关 键 词：聚氯乙烯/聚酯复合材料 阻燃性能 极限氧指数 透光率 

分 类 号：TS106.5[轻工技术与工程—纺织工程]