Facile Preparation of Polypeptides:Moisture Insensitive and Superfast Ring Opening Polymerization of N-Carboxyanhydrides  

作　　者：栾世方 

机构地区：[1]State Key Laboratory of Polymer Physics and Chemistry,Changchun Institute of Applied Chemistry,Chinese Academy of Sciences

出　　处：《材料导报》2019年第1期1-2,共2页Materials Reports

摘　　要：(a)NCA polymerization initiated by LiHMDS or other initiators in THF,initiator i)n-hexylamine,ii)HMDS,iii)bipyNi(COD);(b)LiHMDS-initiated open vessel polymerization of BLGNCA at 26 mg and 2 g scale;(c)GPC traces of poly-BLG at variable DP;(d)Reaction rates of LiHMDS and hexylamine initiated BLGNCA polymerization in THF with NCA:initiator ratio of 100∶1 and initial NCA concentration at 0.2 mol/L;(e)CD spectra of poly-BLG at variable DP prepared from LiHMDS-initiated NCA polymerization.

关 键 词：FACILE PREPARATION polypeptides:moisture insensitive 

分 类 号：TB[一般工业技术]