氢致变色镁基功能薄膜研究进展  

Research Progress of Hydrogen-Chromic Magnesium-Based Thin Films

作　　者：彭立明[1,2] 刘越[1,2] 陈娟 丁文江 PENG Liming;LIU Yue;CHEN Juan;DING Wenjiang(State Key Laboratory of Metal Matrix Composites,School of Materials Science and Engineering,Shanghai Jiao Tong University,Shanghai 200240,China;National Engineering Research Center of Light Alloy Net Forming,School of Materials Science and Engineering,Shanghai Jiao Tong University,Shanghai 200240,China)

机构地区：[1]上海交通大学材料科学与工程学院金属基复合材料国家重点实验室,上海200240 [2]上海交通大学材料科学与工程学院轻合金精密成型国家工程研究中心,上海200240

出　　处：《中国材料进展》2018年第12期970-977,993,共9页Materials China

基　　金：科技部国家重点研发专项(2016YFB0301001);高等学校学科创新引智计划(B16032).

摘　　要：氢致变色薄膜是一种新型功能材料,其以具有可逆吸放氢特性的复合薄膜为核心,通过氢化和脱氢实现透明态和反射态之间的转换,对可见及红外波段光谱都具有智能调控性,因而可被广泛应用于智能调光节能窗和氢气传感器等领域。镁具有较高的储氢能力,而且产量丰富,易与多种元素复合,这些优势使得镁基材料在氢能源方面发挥着越来越重要的作用。镁基薄膜器件具有结构简单、响应速度快、光学调控范围广和可持续性强等优点,是目前主要的氢致变色功能薄膜材料。综述了氢致变色镁基薄膜在智能窗和光纤传感器领域的研发过程、变色原理以及复合体系,同时对研究现状中存在的各类问题和改性机制进行了简要分析,并就氢致变色镁基薄膜材料的发展趋势进行了展望。As a new functional material,hydrogen-chromic film is mainly composed of a core composite film with reversible hydrogen storage property.It converts between transparent and reflective states through hydrogenation and dehydrogenation,regulates light at the visible and infrared spectrum intelligently.Therefore,it is widely used in smart switchable energy-saving window and hydrogen sensor.Magnesium has high hydrogen storage capacity and abundant output,then it is easy to be combined with various elements,these characteristics make magnesium-based materials play an important role in hydrogen energy application.The magnesium-based thin film device has the advantages such as simple structure,rapid response,wide optical control range and strong sustainability,it is the main hydrogen-chromic film material currently.This paper reviews the research process of hydrogen-chromic magnesium-based films,including their development,color change principle and composite system in the fields of smart window and optic fiber sensor,meanwhile,the current problems and modification mechanisms during the research status are also briefly analyzed,then their future developments are prospected.

关 键 词：氢致变色 镁基薄膜 可逆转换 智能窗 光纤传感 

分 类 号：TK91[动力工程及工程热物理] TB43[一般工业技术]