金属有机骨架在色谱吸附和分离中的应用进展  

Progress in the Application of Metal-organic Frameworks used in Chromatographic Adsorption and Separation

作　　者：秦伟伟 主曦曦[2] QIN Wei-wei;ZHU Xi-xi(Faculty of Geosciences & Environmental Engineering,Southwest Jiaotong University,Chengdu 611756,China;College of Chemical & Environmental Engineering,Shandong University of Science & Technology,Qingdao,Shandong 266590,China)

机构地区：[1]西南交通大学地球科学与环境工程学院,成都611756 [2]山东科技大学化学与环境工程学院,山东青岛266590

出　　处：《四川环境》2019年第1期144-149,共6页Sichuan Environment

基　　金：国家自然科学基金项目(21705133);中央高校基本科研业务费专项资金项目(2682017CX07);山东省自然科学基金项目(ZR2018PEE006)资助

摘　　要：金属有机骨架材料(Metal-organic frameworks, MOFs)是一种大约20年前新兴起的、目前最年轻的多孔复合材料。由于其出色的物理和化学特性, MOFs已被广泛应用于多种领域。色谱技术作为一种重要的分析和分离方法,在环境监测分析和污染治理中起着重要的作用。着重介绍了MOFs在色谱技术中的应用,包括气相色谱(GC)、高效液相色谱(HPLC)及毛细管电色谱(CEC)等。除了MOFs在色谱领域取得的重要影响,也探讨了MOFs作为色谱材料,与传统色谱材料相比所具有的诸多应用前景及局限,以期为将来MOFs的理论和色谱应用研究提供指导。Metal-organic frameworks(MOFs)are currently the youngest class of porous materials emerged approximately twenty years ago.MOFs has been widely used in various fields due to its outstanding physical and chemical properties.As one of the most important analytical and separation methods,chromatography technology has been playing an important role in environmental monitoring analysis and pollution control.This review focused on the application of MOFs in chromatography,including gas chromatography(GC),high-performance liquid chromatography(HPLC)and capillary electrochromatography(CEC),etc.This review also discussed the limitations and prospects of MOFs as chromatographic materials compared to the conventional ones,which are expected to provide useful theories and guidance for the future study of MOFs and their application in chromatography.

关 键 词：金属有机骨架 气相色谱 高效液相色谱 毛细管电色谱 吸附 分离 

分 类 号：X853[环境科学与工程—环境工程]