乙烯齐聚工艺——从非选择性齐聚到选择性齐聚  

Ethylene oligomerization technology——from non-selective oligomerization to selective oligomerization

作　　者：吴昊[1] 毛国梁[1] 王月含 封智超 WU Hao;MAO Guoliang;WANG Yuehan;FENG Zhichao(Provincial Key Laboratory of Oil & Gas Chemical Technology,College of Chemistry and Chemical Engineering,Northeast Petroleum University,Daqing 163318,China;Zhejiang NHU Company Ltd.,Xinchang 312500,China)

机构地区：[1]东北石油大学化学化工学院石油与天然气化工省重点实验室,黑龙江大庆163318 [2]浙江新和成控股集团,浙江新昌312500

出　　处：《化工科技》2019年第1期77-84,共8页Science & Technology in Chemical Industry

基　　金：黑龙江省创新创业训练基金项目(201710220019)

摘　　要：线性α-烯烃是一类重要的有机化工原料,主要通过乙烯齐聚工艺生产。介绍了乙烯非选择性齐聚工艺(包括Chevron工艺、B P Amoco工艺、Shell工艺、Idemitsu工艺、Alfene工艺、Exxom工艺、AlphaSelect工艺)以及乙烯选择性齐聚工艺(包括乙烯三聚及乙烯四聚)的发展现状。分析了乙烯选择性齐聚存在的问题,并指出了今后的发展方向。Linear alpha-olefin is an important class of organic chemical raw material that is produced primarily by the ethylene oligomerization process.The paper mainly introduces the development of the non-selective oligomerization technology of ethylene(including Chevron technology,BPAmoco technology,Shell technology,Idemitsu technology,Alfene technology,Exxom technology,AlphaSelect technology)and ethylene selective oligomerization technology(including ethylene trimerization and ethylene tetramerization).The problem of the selective oligomerization of ethylene is analyzed,and the direction of future development is pointed out.

关 键 词：乙烯 齐聚 齐聚工艺 选择性齐聚 非选择性齐聚 

分 类 号：O632.12[理学—高分子化学]