一种非放射性压裂效果评价用钐标记压裂支撑剂的研制  

Preparation of an Non-radioactive, Samarium-tragged Fracturing Proppant for the Evaluation of Fracturing Effect

作　　者：李灿然[1,2] 李向辉 遆永周[1,2] 邓刚 谢战胜[3] 吕晓华 李甜甜[1,2] 董明静 LI Canran;LI Xianghui;TI Yongzhou;DENG Gang;XIE Zhansheng;LV Xiaohua;LI Tiantian;DONG Mingjing(Isotope Research Institute of Henan Academy of Sciences Co., Ltd., Zhengzhou 450015, Henan, China;Henan Tongxin Technology Co., Ltd., Zhengzhou 450015, Henan, China;Zhengzhou Hazardous Waste and Radiation Environmental Monitoring and Management Center, Zhengzhou 450007, Henan, China)

机构地区：[1]河南省科学院同位素研究所有限责任公司,河南郑州450015 [2]河南省同新科技有限责任公司,河南郑州450015 [3]郑州市危险废物和辐射环境监督管理中心,河南郑州450007

出　　处：《陶瓷学报》2019年第1期57-61,共5页Journal of Ceramics

基　　金：河南省科技攻关项目(182102210076);国家自然科学基金面上项目(41574119);河南省科学院项目(18ZT04012;18ZS04017)

摘　　要：以氧化钐为标记物质,制备了一种非放射性压裂效果评价用钐标记压裂支撑剂,研究了标记元素添加对支撑剂晶型结构、烧结温度、破碎率、酸溶解度的影响,并探索了其相应内在机理。研究发现:标记元素的加入可以降低支撑剂的烧结温度、在69 MPa下破碎率及酸溶解度,主要是因为标记元素与支撑剂中的氧化铝反应生成新晶相,新晶相的生成有助于提高支撑剂致密度、细化刚玉晶粒、提高支撑剂耐酸性。A non-radioactive, samarium-tragged fracturing proppant for the evaluation of fracturing effect was prepared using samarium sesquioxide as the labeled substance. The effects of Sm2O3 addition on the crystal structure, sintering temperature, crush resistance and acid solubility of the proppants were investigated, and the corresponding internal mechanism was explored. The results showed that the labeled element could reduce the sintering temperature, crushing rate and acid solubility, mainly because the formation of a new phase, which was generated by reaction between the labeled element and aluminum oxide, can improve the density, refine corundum grains and enhance the resistance of the support agent to acid.

关 键 词：氧化钐 标记元素 支撑剂 非放射性 压裂效果评价 

分 类 号：TQ174.75[化学工程—陶瓷工业]