脒类化合物的合成工艺研究进展  

Research progress in the synthesis of amidine compounds

作　　者：李珠叶 徐保明[1] 薛东升 叶流颖 李高 廖义鹏 周宝晗[1] 陈驰[1] LI Zhu-ye;XU Bao-ming;XUE Dong-sheng;YE Liu-ying;LI Gao;LIAO Yi-peng;ZHOU Bao-han;CHEN Chi(Hubei University of Technology,Hubei Provincial Graduate Workstation,Wuhan 430068,China;Shanghai Hanjing Chemicals Co.,Ltd.,Shanghai 201615,China)

机构地区：[1]湖北工业大学湖北省研究生工作站,湖北武汉430068 [2]上海汉景化工有限公司,上海201615

出　　处：《应用化工》2019年第2期430-433,共4页Applied Chemical Industry

基　　金：国家自然科学基金(21272086);湖北省自然科学基金计划青年项目(2018CFB359);湖北省大学生创新创业训练计划项目(201710500045)

摘　　要：对脒类化合物的合成方法从两个方面进行了分类总结,分为催化法和缩合法,并对使用不同催化剂及缩合剂的合成方法进行了分析。通过对比各自的优缺点,指出以Ni为催化剂的催化加氢法是一种较好的可用于工业化生产的方法;而微波辅助法是一种可在未来进行深入研究的新方法。The synthesis methods of amidine compounds are classified and summarized from two aspects,which are divided into catalytic method and contraction method,and the synthesis methods of different catalysts and reagents are analyzed.By comparing their advantages and disadvantages,it is pointed out that the catalytic hydrogenation method with Ni as catalyst is a better method for industrial production;and microwave assisted method is a new method which can be further studied in the future.

关 键 词：脒 催化加氢 微波辅助 合成工艺 

分 类 号：TQ225.264[化学工程—有机化工]